The invention relates to an organic electroluminescence device which comprises a substrate, a positive pole, an organic luminescent functional layer, an electronic injection layer and a negative pole, wherein the substrate, the positive pole, the organic luminescent functional layer, the electronic injection layer and the negative pole are sequentially arranged in an overlaid mode. The electronic injection layer is made of a mixture composed of barium compounds and metal. The barium compounds are selected from one of barium hydroxide, barium carbonate, barium nitrate and barium sulfate, and the metal is selected from one of silver, aluminum, samarium, ytterbium and alloy of the silver, the aluminum, the samarium and the ytterbium. In the mixture, the mass percent of the barium compounds is 35-80%. The mixture composed of the barium compounds and the metal has the excellent electronic injection performance, the electronic mobility can be improved, the starting voltage of the organic electroluminescence device can be reduced, the quenching harmful effect of halogen atoms on emitted light can be avoided, and the luminous efficiency is high. The invention further provides a manufacturing method of the organic electroluminescence device, another organic electroluminescence device and the manufacturing method of the organic electroluminescence device.