The invention relates to composite biochemical, coupled physicochemical, and heavy-metal-removing sewage treatment process and technology. The invention mainly discloses a continuous operation system composed of a mechanical solid-liquid separation unit, a composite biochemical treatment unit, a coupling physicochemical treatment unit, and a waste comprehensive utilization unit. According to the invention, a plant capillary biofilm bed technology, a shrub-type plant heavy metal removing technology, a flocculation complexation reaction technology, an inorganic membrane filtration technology, and optical, electrical, and membrane coupled desalination technology are adopted, such that harmful substances and heavy metal elements in sewage can be effectively removed. Treated water reaches a discharge standard, and can be recycled. Also, according to the invention, with microbial fermentation technology and high-temperature cracking technology, waste, sludge, and shrub-type plant fuel-wood are converted into nutritive soil, active carbon, tar and electrical power, such that waste is turned valuable, and pollutant discharge reduction or zero discharge is realized. The process and technology provided by the invention can be applied in organic sewage and industrial sewage treatment, and especially provides a good treatment effect against garbage leachate.