The invention relates to a preparation method of an aqueous
polyurethane emulsion with a high
solid content. The method comprises the following steps: first, adding
polymer polyol, polyisocyanates, catalyst and chain
extender into a reactor according to certain steps, and controlling hydrophilic groups to distribute on molecular chain ends; then adding polyisocyanates to form a performed
polymer terminated with an NCO group; then reducing
system temperature, adding a neutralizer for
neutralization, adding deionized water, and stirring with high speed to carry out water dispersion; at last, adding a post chain
extender to carry out chain extension in water; removing the solvents under a reduced pressure after reaction to obtain the aqueous
polyurethane emulsion. According to the invention, hydrophilic efficiency of the hydrophilic groups is raised to lower intake amount of hydrophilic groups, and a small amount of solvents are added in the reaction to lower a
system viscosity. The aqueous
polyurethane emulsion prepared by the invention has characteristics of high
solid content, low
viscosity, good
water resistance and stabile storage, and can be used in industries of paint,
adhesive, leather finishing and fabric arrangement, etc.