The invention relates to arc preventing work clothes made of waterproof and warm fabric. The arc preventing work clothes comprise a work clothes body, wherein flame-resistant material is added into the apparel fabric; the arc preventing work clothes are produced by the steps of: padding with flame-resistant finishing liquid (at room temperature), pre-drying, smoking with ammonia, oxidizing and washing, drying, preshrinking, and thereby forming finished product; a base cloth layer is also compounded on the back of the work clothes body; the base cloth layer comprises a surface layer on which a waterproof layer is arranged, an inner layer is arranged below the surface layer, and a thermal layer that is made of thermal cotton is arranged between the surface layer and the inner layer. By using the arc preventing work clothes made of waterproof and warm fabric, harm to human skin in contact with the heat energy of the arc can be reduced to the minimal. The arc preventing work clothes made of waterproof and warm fabric have the advantages of being breathable, waterproof, warm-keeping and low-cost.