The invention provides a preparation method for a composite metal layer plated buckypaper composite material. The preparation method comprises the following steps that buckypaper sequentially undergoes acidification, sensitization and activation treatment, and then is added into deionized water for ultrasonic treatment, then a reducing agent is added, uniform mixing is performed to obtain a suspension liquid, then a nickel plating solution is added into the suspension liquid, and the nickel-plated buckypaper is obtained through reaction; mixed powder of tungsten oxide and molybdenum oxide is sprayed on the surface of the nickel-plated buckypaper, water-passing hydrogen is introduced after heating, and the modified nickel-plated buckypaper is obtained through reaction; the modified nickel-plated buckypaper is added into a copper plating solution, then the reducing agent is added, and a precursor of the composite metal layer plated buckypaper composite material is obtained through reaction; and the precursor is reduced under a reducing atmosphere, then sintering is performed, and the composite metal layer plated buckypaper composite material is obtained. The method is beneficial to improving the mechanical property, the electrical property and the service performance of the composite material, has the characteristics of being short in process, simple in equipment and high in safety operability, and enables continuous production to be realized easily.