To provide an efficient method for producing a non-cross-linked
cyclic oligosaccharide-modified organopolysiloxane soluble in solvents despite its high molecular weight, by removing unreacted cyclic oligosaccharides.SOLUTION: A method for producing a
cyclic oligosaccharide-modified organopolysiloxane comprises the following steps: [Step 1] obtaining an
oligosaccharide-modified organopolysiloxane by
hydrosilylation of a composition containing (A) to (D) in the following, namely, (A) an organohydrogen polysiloxane having one or more hydrosilyl groups per molecule having a kinematic
viscosity of 50 mm2 / s or more at 25°C and a number average molecular weight of 8,000 or more, (B) a
cyclic oligosaccharide derivative having an unsaturated group represented by the specified general formula (1), (C) a
hydrosilylation catalyst, and (D) an
organic solvent; [Step 2] cleaning and filtering the cyclic
oligosaccharide-modified organopolysiloxane obtained in the Step 1 with a cleaning
organic solvent having a
relative permittivity of 23 or more at 25°C or a mixture of such solvents; and [Step 3] removing the organic solvents used in the Steps 1 and 2.SELECTED DRAWING: None