The invention discloses a WO3-x nanosheet photocatalyst with visible light region LSPR absorption as well as a preparation method and application thereof. Tungsten powder, hydrogen peroxide and isopropanol are used as raw materials, a solvothermal method is adopted for preparing a nano tungsten oxide hydrate, then high-temperature reduction is performed to obtain the WO3-x nanosheet photocatalyst,so that LSPR absorption and regulation of WO3-x in a visible light region are achieved, wherein the absorption peak wavelength is smaller than 520 nm. The preparation method comprises the following steps: S1, mixing tungsten powder and a hydrogen peroxide aqueous solution, reacting, adding isopropanol, and heating the reactants to 150-170 DEG C in a high-pressure kettle for reaction to obtain a nano tungsten oxide hydrate; and S2, adding the nano tungsten oxide hydrate in a reducing atmosphere, and carrying out heat treatment to obtain the WO3-x nanosheet photocatalyst with visible light region LSPR absorption. The obtained catalyst has strong LSPR absorption in the whole visible light region, thermal charges generated by plasmon excitation can directly catalyze and degrade organic matters, and the catalytic degradation rate of methyl orange can reach 93%.