The present invention discloses a lead-free glass container produced though a thermal transfer printing process, and belongs to the field of glass manufacturing. According to the present invention, lead-free white broken glass, white quartz sand, soda ash, sodium feldspar, calcite, sodium sulfate, cobalt powder, and a heat-resistant substrate film with color pattern are adopted as raw materials, and lead-free glass container manufacturing and thermal transfer printing are performed to obtain the finished product. According to the present invention, the method has characteristics of simple production, less production steps, high efficiency, no pollution, small occupation area and less investment, the pattern printed on the glass container surface has characteristics of good adhesion, high gloss, clear pattern, accurate chromatic printing, bright color, safety and no toxicity, and after lettering is performed, oil spraying sand blasting, secondary injection molding and other post-treatments can be performed.