The invention discloses a slag powder-doped composition for preparing white facing as-cast finish concrete. The composition is characterized by consisting of the following components in parts by weight: 180-260 parts of cement, 85-110 parts of water, 330-390 parts of sand, 500-580 parts of stone, 2.0-4.0 parts of additive, 1 part of titanium dioxide and 20-60 parts of slag powder. In the composition disclosed by the invention, the proportion of the components is more scientific and reasonable, and the working performance meets the requirements on concrete pumping and pouring; and moreover, the bleeding and separation are avoided, the shrinkage is low, and the formed concrete is dense and has strong texture. With the formula, the large-flow regime white as-cast finish concrete has the advantages of good fluidity, good workability, good water-retaining property, low slump loss, strong pumpability and the like in concrete construction; and the strength of the formed concrete can be guaranteed, the surface gloss is good, and the chromatic aberration meets the requirement on the quality of the facing as-cast finish concrete.