The invention discloses an antidandruff and antipruritic liquid shampoo containing nano carbon crystals, and belongs to the field of chemical necessities. The antidandruff and antipruritic liquid shampoo is prepared from, by weight, 0.5-1.5 parts of nano carbon crystals, 30-40 parts of Chinese honeylocust fruit, 15-20 parts of tea seeds, 15-20 parts of cacumen platycladi, 15-20 parts of radix polygoni multiflori, 15-20 parts of fresh ginger, 15-20 parts of mulberry leaves, 20-25 parts of radix angelicae sinensis, 10-15 parts of ganoderma lucidum, 10-15 parts of black sesame, 15-20 parts of lotus leaves, 15-20 parts of honey and 10-15 parts of walnut kernels. The invention further discloses a preparation method of the antidandruff and antipruritic liquid shampoo containing the nano carbon crystals. The antidandruff and antipruritic liquid shampoo containing the nano carbon crystals can effectively remove dirt, bacteria, aged horniness, scurf, grease and the like on hairs and scalp, a good hair cleaning effect is achieved, damaged hairs can be repaired, the hairs are smooth, fresh, cool and convenient to comb, and meanwhile the scalp can be nursed.