The invention discloses a preparation method for preparing an ordered membrane
electrode by using a two-step electrodeposition method and the membrane
electrode. Comprising the following steps: S1, providing a
gas diffusion layer, and forming a hydrophilic layer on the surface of a microporous layer of the
gas diffusion layer; s2, first electro-deposition: dipping a product in the step S1 into a
platinum-containing electro-deposition solution, depositing
metal Pt particles on the surface of the hydrophilic layer, and
drying for later use after the reaction is completed; s3, second electrodeposition: dipping a product in the step S2 into a perfluorinated
sulfonic acid resin solution, and depositing a perfluorinated
sulfonic acid resin film on the surface of the
metal Pt particles to form a
cathode catalyst layer; and S4, sequentially laminating the product in the step S3 with a
proton exchange membrane and an
anode diffusion layer, and compounding by a hot-pressing method to obtain the ordered membrane
electrode. According to the invention, the hydrophilic layer containing the amino
silane coupling agent is formed on the surface of the microporous layer, so that anchoring and uniform distribution effects on subsequent electro-deposited Pt nano-particles are achieved, and the effective contact area and stability of Pt are increased; the surfaces of the Pt particles are coated with the perfluorinated
sulfonic acid resin film, so that a three-phase interface is effectively constructed, an effective reaction region is expanded to the whole
cathode catalyst layer, and the
reaction rate of the membrane electrode and the performance of the battery are improved.