The invention belongs to the technical field of luminescent macromolecular
composite material, and particularly relates to a method for preparing a sulfhydryl functional
rare earth-macromolecular composite
luminescent material. In the method, firstly, by adopting an
organic synthesis method, aromatic organic micro molecules are grafted in an inorganic silica skeleton to obtain organic bridge precursor; the organic bridge precursor, polymers and
rare earth ions are further combined to obtain the
rare earth macromolecular material by chemical action; at last, by the
sol-
gel method, all obtained materials are subjected to polyreaction to obtain dried gel, so that the organic macromolecular polymers with long carbon chains are embedded in silica network substrate by
covalent bond; and the dried gel is subjected to dry
ageing to obtain the macromolecular
composite material with stable chemical and thermodynamic performances,
smooth surface appearance and special
luminescence emission. The method has the advantages of simple preparation process, mild experimental conditions, strong
operability, good reproductivity, low cost, stable quality of obtained products and order appearance, and the sizes of
crystal grains can be controlled in the range of micron and nanometer.