The invention discloses a preparation method for a composite conductive polymer coated with elemental sulfur and applications, and belongs to the electrochemical energy storage field. Concretely, a suspension containing pyrrole, aniline and thiophene monomers and elemental sulfur is employed as a supporting electrolyte, a platinum electrode is employed as an auxiliary electrode, aluminum foil is employed as a working electrode, a saturated calomel electrode is employed as a reference electrode, electrochemical parameters are adjusted, and polymerization of conductive polymer monomers is controlled while aggregation of elemental sulfur can be controlled synchronously. A polypyrrole / polyaniline / polythiophene composite conductive polymer film coated with elemental sulfur can be formed on the surface of the aluminum foil, and elemental sulfur can be bonded with polythiophene through S-S bonds. The composite conductive polymer film coated with elemental sulfur can be used as a positive pole piece of a lithium-sulfur battery directly, and the aluminum foil is employed as a positive pole current collector. The technology omits a combination process of elemental sulfur and a conductive polymer, and omits a later preparation process of introducing bonding agents during the pole piece preparation process. Operation is simple, and the swelling problem of a positive pole of a lithium-sulfur battery can be solved effectively.