48 results about "Aryl amination" patented technology

One aspect of the present invention relates to ligands for transition metals. A second aspect of the present invention relates to the use of catalysts comprising these ligands in various transition-metal-catalyzed carbon-heteroatom and carbon-carbon bond-forming reactions. The subject methods provide improvements in many features of the transition-metal-catalyzed reactions, including the range of suitable substrates, number of catalyst turnovers, reaction conditions, and efficiency. For example, improvements have been realized in transition metal-catalyzed: aryl amination reactions; aryl amidation reactions; Suzuki couplings; and Sonogashira couplings. In certain embodiments, the invention relates to catalysts and methods of using them that operate in aqueous solvent systems.

One aspect of the present invention relates to ligands for transition metals. A second aspect of the present invention relates to the use of catalysts comprising these ligands in various transition-metal-catalyzed carbon-heteroatom and carbon-carbon bond-forming reactions. The subject methods provide improvements in many features of the transition-metal-catalyzed reactions, including the range of suitable substrates, number of catalyst turnovers, reaction conditions, and efficiency. For example, improvements have been realized in transition metal-catalyzed: aryl amination reactions; aryl amidation reactions; Suzuki couplings; and Sonogashira couplings. In certain embodiments, the invention relates to catalysts and methods of using them that operate in aqueous solvent systems.

The present invention provides methodology for carbon-nitrogen bond formation via vinyl or aryl amination. In the process of the invention, an sp.sup.2 hybridized radical is reacted with an azomethine moiety to form pyrrolidine and indole compounds. The methodology provides a facile process for the synthesis of compounds having the pyrrolidine or indole subunit and is especially advantageous for compounds having acid or base labile functional groups andor is comprised of chiral centers susceptible to acidbase epimerization.

The present invention aims to provide an organic compound which functions as a material for a highly efficient and highly durable organic EL element, exhibits the excellent hole injection and hole transport performance, has electronic stopping power, and exhibits the excellent properties of being highly stable as a thin film and having high light emission efficiency; and the organic EL element which uses the compound and exhibits high durability and high efficiency. The organic EL element is characterized by being provided with a first hole transport layer, a second hole transport layer, a green light-emitting layer, and an electron transport layer which are positioned between a positive electrode and a negative electrode orderly from the positive electrode side, and comprising an arylamine compound represented by general formula (1) and contained in one or more layers among the layered films positioned between the electron transport layer and the first hole transport layer or the second transport layer. (In the formula, Ar1, Ar2, Ar3 and Ar4 may be identical to or different from one another, and represent a substituted or unsubstituted aromatic hydrocarbon group, a substituted orunsubstituted aromatic heterocyclic group, or a substituted or unsubstituted condensed polycyclic aromatic group. L1 represents a substituted or unsubstituted aromatic hydrocarbon divalent group, a substituted or unsubstituted aromatic heterocyclic divalent group, or a substituted or unsubstituted condensed polycyclic aromatic divalent group. R1, R2 and R3 represent a hydrogen atom, a deuterium atom, a fluorine atom, a chlorine atom, a cyano group, a nitro group, a C1-6 straight-chain or branched alkyl group which may have a substituent group, a C5-10 cycloalkyl group which may have a substituent group, a C2-6 straight-chain or branched alkenyl group which may have a substituent group, a C1-6 straight-chain or branched alkyloxy group which may have a substituent group, a C5-10 cycloalkyloxy group which may have a substituent group, a substituted or unsubstituted aromatic hydrocarbon group, a substituted or unsubstituted aromatic heterocyclic group, a substituted or unsubstituted condensed polycyclic aromatic group, or a substituted or unsubstituted aryloxy group. n is an integer of 1-3, inclusive.)

The present invention relates to processes for producing a diaryl amine compound of the formula (I); or a salt thereof, said process comprising the step of coupling a compound of formula (II) with an amine of formula (III) in the presence of an alkali metal salt or a transition metal catalyst, wherein: Ar1 and Ar2 are independently Q; wherein each Q is an aryl or heteroaryl ring system optionally fused to a saturated or unsaturated 5-8 membered ring having 0-4 heteroatoms; wherein Q is optionally substituted as defined in claim 1, wherein: X is a leaving group; and Y is -C(O)-O-Z; and Z is selected from C1-C6 aliphatic, benzyl, Fmoc, -SO2R' and Q, provided that Q is not substituted with X or alkyne; wherein R' is as defined in claim 1.

The purpose of the present invention is to provide an organic EL element which (1) has high luminous efficiency and high power efficiency, (2) has a low light emission start voltage, (3) has a low practical driving voltage, and (4) particularly has a long service life. According to the present invention, an organic electroluminescent (EL) element is provided, which is provided with at least a positive electrode, a hole injection layer, a first hole transport layer, a second hole transport layer, a light-emitting layer, an electron transport layer and a negative electrode in this order and is characterized in that the second hole transport layer contains an arylamine compound represented by general formula (1) and the electron transport layer contains a pyrimidine derivative represented bygeneral formula (2). In general formula (2), A represents a monovalent group represented by structural formula (3).

[Problem] The purpose of the present invention is to provide an organic EL element in which various materials for an organic EL element, which excel in hole injection / transport performance, electron injection / transport performance, electron blocking performance, stability in a thin film state, and durability, are combined so that properties of each of the materials can be effectively demonstrated,thereby achieving (1) high luminous efficiency and power efficiency, (2) low luminescence starting voltage, (3) low practical driving voltage, and (4) particularly long service life. [Solution] An organic EL element having at least a positive electrode, a hole transportation layer, a light emission layer, an electron transportation layer, and a negative electrode in the stated order, wherein theorganic EL element is characterized in that the hole transportation layer includes an arylamine compound represented by general formula (1), and the electron transportation layer includes a compound having a benzoazole ring structure represented by general formula (2). (1) (In the formula, Ar1-Ar5 may be identical to each other or different from each other, and represent a substituted or unsubstituted aromatic hydrocarbon group, a substituted or unsubstituted aromatic heterocyclic group, or a substituted or unsubstituted fused polycyclic aromatic group. Ar6-Ar8 may be identical to each other or different from each other, and represent a hydrogen atom, a substituted or unsubstituted aromatic hydrocarbon group, a substituted or unsubstituted aromatic heterocyclic group, or a substituted or unsubstituted fused polycyclic aromatic group. n1 represents 0, 1, or 2. Ar3 and Ar4 may form a ring with a single bond or may form a ring so as to be bonded via a substituted or unsubstituted methylene group, an oxygen atom, or a sulfur atom. Ar3 or Ar4 may form a ring with a single bond with a benzene ring to which an Ar3Ar4-N group is bonded, and may form a ring so as to be bonded to each othervia a substituted or unsubstituted methylene group, an oxygen atom, or a sulfur atom.) (2) (In the formula, Ar9 and Ar10 may be identical to each other or different from each other, and represent a hydrogen atom, a deuterium atom, a substituted or unsubstituted aromatic hydrocarbon group, a substituted or unsubstituted aromatic heterocyclic group, a substituted or unsubstituted fused polycyclic aromatic group, or a substituted or unsubstituted alkyl group. Y1 represents a substituted or unsubstituted aromatic hydrocarbon group, a substituted or unsubstituted aromatic heterocyclic group, a substituted or unsubstituted fused polycyclic aromatic group, or a substituted or unsubstituted alkyl group. X represents an oxygen atom or a sulfur atom. Z1 and Z2 may be identical to each other or different from each other, and represent a carbon atom or a nitrogen atom).

An object of the present invention is to provide an organic EL device having (1) high luminous efficiency and high power efficiency, (2) low turn on voltage, (3) low actual driving voltage, and (4) particularly a long lifetime by combining various materials for an organic EL device having excellent hole and electron injection / transport performances, electron blocking ability, stability in a thin-film state, and durability so as to allow the respective materials to effectively reveal their characteristics. The organic EL device has at least an anode, a hole transport layer, a light emitting layer, an electron transport layer and a cathode in this order, the hole transport layer includes an aryl amine compound represented by the following general formula (1), and the electron transport layerincludes a compound having a benzoazole ring structure represented by the following general formula (2).

An organic electroluminescent device having low driving voltage, high luminous efficiency, and a long lifetime is provided by combining various materials for an organic electroluminescent device. In the organic electroluminescent device having at least an anode, a hole injection layer, a first hole transport layer, a second hole transport layer, a light emitting layer, an electron transport layer, and a cathode in this order, the hole injection layer includes an arylamine compound of the following general formula (1) and an electron acceptor.In the formula, Ar1 to Ar4 may be the same or different, and represent a substituted or unsubstituted aromatic hydrocarbon group, a substituted or unsubstituted aromatic heterocyclic group, or a substituted or unsubstituted condensed polycyclic aromatic group.

An organic electroluminescent device having high efficiency, low driving voltage and a long lifetime is provided by combining various materials for an organic electroluminescent device, which are excellent, as materials for an organic electroluminescent device having high efficiency and high durability, in hole and electron injection / transport performances, electron blocking ability, stability in a thin-film state and durability, so as to allow the respective materials to effectively reveal their characteristics. In the organic electroluminescent device having at least an anode, a hole transport layer, a light emitting layer, an electron transport layer and a cathode in this order, the hole transport layer includes an arylamine compound represented by the following general formula (1), and the light emitting layer comprises an amine derivative of the following general formula (2) having a condensed ring structure.

The present invention provides an organic EL element having, in the indicated sequence, at least an anode, a hole injection layer, a hole transport layer, a light-emitting layer, an electron transportlayer, and a cathode, the organic EL element being characterized in that the hole injection layer contains an arylamine compound represented by general formula (1) and an electron acceptor. The organic EL element according to the present invention provides a higher light emission efficiency and a better durability than heretofore while retaining the same low drive voltage as heretofore.

In the organic electroluminescent device having at least an anode, a hole injection layer, a hole transport layer, a light emitting layer, an electron transport layer and a cathode in this order, the hole injection layer includes an arylamine compound of the following general formula (1) and an electron acceptor.In the formula, Ar1 to Ar4 may be the same or different, and represent a substituted or unsubstituted aromatic hydrocarbon group, a substituted or unsubstituted aromatic heterocyclic group, or a substituted or unsubstituted condensed polycyclic aromatic group.

A sensing element for use in the detection of an analyte based on a luminescent response, the sensing element comprising a luminescent triaryl amine compound provided as a coating on a substrate.

The purpose of the present invention is to provide an organic EL element in which a capping layer is combined with various materials of the element so that properties of each of the materials of the element can be effectively demonstrated. The capping layer is constituted from a material that does not affect material inside the organic EL element when sunlight having wavelengths of 400-410 nm is absorbed, that has a high absorption coefficient and a high refractive index in order to greatly improve light extraction efficiency, that gives a thin film having excellent stability, durability and lightfastness, and that does not absorb light in the blue, green and red wavelength regions. The invention relates to: an arylamine compound having a benzoazole ring structure; and an organic EL element having a capping layer that contains the arylamine compound, and a luminescent layer that contains a host and a phosphorescent dopant.

The triarylamine compound is represented by the following general formula (1), and the material, the optical element, and the optical apparatus each include a polymerized product (cured product) of the triarylamine compound.(In the general formula (1), R1 and R2 are each independently selected from a substituted or unsubstituted alkyl group having 1 to 10 carbon atoms, and a substituted or unsubstituted alkylene group having 1 to 8 carbon atoms, the alkylene group having a polymerizable functional group, and R3 to R12 are each independently selected from a hydrogen atom, a cyano group, a trifluoromethyl group, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkylene group having a polymerizable functional group, and a polymerizable functional group, provided that at least one of R3 to R12 represents an electron-withdrawing group, and at least one of R1 to R12 has a polymerizable functional group.)

Provided is a charge-transporting varnish which includes a charge-transporting material including fluorine atoms, a charge-transporting material not including fluorine atoms, a dopant material comprising heteropoly acid, and an organic solvent, said charge-transporting material including fluorine atoms being a polymer of weight-average 1,000 to 200,000 molecular weight obtained by condensing a triarylamine compound, an aryl aldehyde compound including fluorine atoms, and a fluorine derivative having a carbonyl group, and said charge-transporting material not including fluorine atoms being an oligoaniline compound. The charge-transporting varnish provides a thin film which, even in a case of being used as a single layer in contact with and in between an anode and a luminescent layer, is capable of achieving an organic EL element having superior luminance characteristics and durability.

The present invention addresses the problem of providing an organic EL element that is equipped with a capping layer configured from two layers, which are a first capping layer and a second capping layer having a higher refractive index than the first capping layer, with a view to achieving an improved light extraction efficiency as compared with an organic EL element formed from a unilaminar capping layer. The present invention pertains to an organic electroluminescence element which at least has an anode, a hole transport layer, a light-emitting layer, an electron transport layer, a cathode, and a capping layer in this order, wherein: the capping layer is structured to have two layers consisting of a first capping layer and a second capping layer; within a wavelength range of 450-650 nm, the second capping layer has a greater refractive index than the first capping layer; and the second capping layer comprises an aryl amine compound having a specific structure.