The invention discloses 1, 4: 3, 6-dianhydro-D-glucopyranose
carbonate, which has the following
structural formula: # imgabs0 #, in which R is phenyl or methyl. The preparation method of the 1, 4: 3, 6-dianhydro-D-glucopyranose carbonic ester comprises the following steps: adding raw materials 1, 4: 3, 6-dianhydro-D-glucopyranose and
alcohol into a high-pressure reaction kettle, then sequentially adding a catalyst, a ligand and methylbenzene, replacing air in the reaction kettle with
carbon dioxide, increasing the pressure of the
carbon dioxide in a
reaction system to 5.0-10.0 MPa, carrying out heat preservation for 2-3 hours, and carrying out heat preservation for 2-3 hours, so as to obtain the 1, 4: 3, 6-dianhydro-D-glucopyranose carbonic ester. Then heating and reacting at 150 to 200 DEG C for 24 hours; after the reaction is finished, cooling a
reaction system to normal temperature and normal pressure, performing extraction separation on reaction liquid to obtain an organic phase,
drying with
anhydrous sodium sulfate, performing reduced-pressure
evaporation to remove the
solvent, and performing
column chromatography separation on
solid residues to obtain a target product. According to the present invention, the 1, 4: 3, 6-dianhydro-D-glucopyranose
carbonate is synthesized by using the 1, 4: 3, 6-dianhydro-D-glucopyranose as the starting material; when the spice is added into the cigarette, the cigarette fragrance can be enriched, the
smoke permeability and the fine degree are improved, and the potential application value is achieved.