The invention provides a negative ion ceramic tile. The negative ion ceramic tile comprises a green body layer and a glaze layer, the glaze layer is prepared from the following raw materials in partsby weight: 3-5 parts of negative ion powder, 30-50 parts of attapulgite, 20-40 parts of porous diatomite, 8-15 parts of microcrystalline glass, 20-30 parts of titanium dioxide, 5-10 parts of zinc oxide, 2-3 parts of modified phenolic resin and 1-5 parts of a titanate coupling agent; the preparation method of the negative ion powder comprises the following steps: mixing tourmaline powder, nano cuprous oxide, stannic chloride and nano zinc oxide, heating at 200 DEG C for 1 hour, heating at 350 DEG C for 1 hour to obtain a primary sinter, adding iron pentahydrate, LiTFSi and silicone, uniformly mixing, sintering at 500 DEG C in a nitrogen atmosphere, and pulverizing to 200 meshes, wherein the modified phenolic resin is modified by adding 0.5% of 1, 3-dimethylimidazole dimethyl phosphate salt.