96 results about "Asphaltene precipitation" patented technology

The present invention provides a downhole method and apparatus using a flexural mechanical resonator, for example, a tuning fork to provide real-time direct measurements and estimates of the viscosity, density and dielectric constant of formation fluid or filtrate in a hydrocarbon producing well. The present invention additionally provides a method and apparatus for monitoring cleanup from a leveling off of viscosity or density over time, measuring or estimating bubble point for formation fluid, measuring or estimating dew point for formation fluid, and determining the onset of asphaltene precipitation. The present invention also provides for intercalibration of plural pressure gauges used to determine a pressure differential downhole.

The invention comprises an apparatus and method for simple fluorescence spectrometry in a downhole environment using a UV light source and UV fluorescence to determine a parameter of interest for a sample downhole. The UV light source illuminates the fluid, which in turn fluoresces light. The fluoresced light is transmitted back towards the UV light source and through the pathway towards an optical spectrum analyzer. API gravity is determined by correlation the wavelength of peak fluorescence and brightness of fluorescent emission of the sample. Asphaltene precipitation pressure is determined by monitoring the blue green content ratio for a sample under going depressurization.

The present invention provides a downhole spectrometer for determination of dew point pressure to determine an associated optimal pumping rate during sampling to avoid precipitation of asphaltenes in a formation sample. A sample is captured at formation pressure in a controlled volume. The pressure in the controlled volume is reduced. Initially the formation fluid sample appears dark and allows less light energy to pass through a sample under test. The sample under test, however, becomes lighter and allows more light energy to pass through the sample as the pressure is reduced and the formation fluid sample becomes thinner or less dense under the reduced pressure. At the dew point pressure, however, the sample begins to darken and allows less light energy to pass through it as apshaltenes begin to precipitate out of the sample. Thus, the dew point is that pressure at which peak light energy passes through the sample. The dew point pressure is plugged into an equation to determine the optimum pumping rate for a known mobility, during sampling to avoid dropping the pressure down to the dew point pressure to avoid asphaltene precipitation or dew forming in the sample. The bubble point can be plugged into an equation to determine the optimum pumping rate for a known mobility, during sampling to avoid dropping the pressure down to the bubble point pressure to avoid bubbles forming in the sample.

The present invention provides a down hole spectrometer for determination of dew point pressure to determine an associated optimal pumping rate during sampling to avoid precipitation of asphaltenes in a formation sample. A sample is captured at formation pressure in a controlled volume. The pressure in the controlled volume is reduced. Initially the formation fluid sample appears dark and allows less light energy to pass through a sample under test. The sample under test, however, becomes lighter and allows more light energy to pass through the sample as the pressure is reduced and the formation fluid sample becomes thinner or less dense under the reduced pressure. At the dew point pressure, however, the sample begins to darken and allows less light energy to pass through it as apshaltenes begin to precipitate out of the sample. Thus, the dew point is that pressure at which peak light energy passes through the sample. The dew point pressure is plugged into an equation to determine the optimum pumping rate for a known mobility, during sampling to avoid dropping the pressure down to the dew point pressure to avoid asphaltene precipitation or dew forming in the sample. The bubble point can be plugged into an equation to determine the optimum pumping rate for a known mobility, during sampling to avoid dropping the pressure down to the bubble point pressure to avoid bubbles forming in the sample.

The present invention provides a downhole method and apparatus using a flexural mechanical resonator, for example, a tuning fork to provide real-time direct measurements and estimates of the viscosity, density and dielectric constant of formation fluid or filtrate in a hydrocarbon producing well. The present invention additionally provides a method and apparatus for monitoring cleanup from a leveling off of viscosity or density over time, measuring or estimating bubble point for formation fluid, measuring or estimating dew point for formation fluid, and determining the onset of asphaltene precipitation. The present invention also provides for intercalibration of plural pressure gauges used to determine a pressure differential downhole. A hard or inorganic coating is placed on the flexural mechanical resonator (such as a tuning fork) to reduce the effects of abrasion from sand particles suspended in the flowing fluid in which the flexural mechanical resonator is immersed.

Compositions comprising at least one C4-C30 olefin or oxidation product thereof and kerosene or an aromatic solvent are particularly effective for use in removing asphaltene and asphaltene-containing organic deposits and in preventing or reducing the precipitation and deposition of asphaltenes from hydrocarbon fluids. When added to heavy oils comprising asphaltenes, alone or in combination with dispersants and further inhibitors, the invented compositions lower viscosity and pour point, and aid in preventing asphaltene precipitation during transport and in combustion.

Performance of equipment, such as a desalter, in a refinery is monitored in real-time and on-line to minimize fouling of downstream equipment. Using an instrument to measure particles and droplets in-process allows monitoring of the various operations to optimize performance. Such measurement can also be used during crude oil blending to detect asphaltene precipitates that can cause fouling and can be used for monitoring other fouling streams.

Trunk piston marine engine lubrication, when the engine is fueled by heavy fuel oil, is effected by a composition comprising a major amount of an oil of lubricating viscosity containing at least 50 mass % of a basestock containing greater than or equal to 90% saturates and less than or equal to 0.03% sulphur or a mixture thereof, and respective minor amounts of an overbased metal hydrocarbyl-substituted hydroxybenzoate detergent other than such a detergent having a basicity index of less than two and a degree of carbonation of 80% or greater and at least 1 mass % of a hydrocarbyl-substituted carboxylic acid, anhydride, ester or amide thereof. Asphaltene precipitation in the lubricant, caused by the presence of contaminant heavy fuel oil, is prevented or inhibited.