The invention discloses a batch extraction-rectification-separation method of a dichloromethane-methanol azeotropic mixture, and belongs to the separation technology of the rectification-separation method of dichloromethane-methanol azeotropic mixture. The method comprises the following steps of: by taking propanol, isopropanol, 1,3-propanediol, glycol, tertiary butanol, N,N-dimethylformamide or dimethyl sulfoxide as an extracting agent, wherein the mass ratio of the extracting agent to an overhead is (0.5:1)-(10:1) under normal pressure or reduced pressure, and the feeding temperature of the extraction agent ranges from 20 to 40 DEG C; controlling different temperatures at the top of an extracting rectifying tower or different reflux ratios, and obtaining a dichloromethane product, a dichloromethane-methanol transition section I, a methanol product and a methanol-extracting agent transition section II from the top of the extracting rectifying tower, respectively; when the constitution of the extracting agent of a heating kettle meets the requirements, pumping the extraction agent into a high-position storage tank, and feeding materials for next batch extraction-rectification-separation. The batch extraction-rectification-separation method of the dichloromethane-methanol azeotropic mixture has the advantages that high-purity methanol and dichloromethane products are separated out by breaking the dichloromethane-methanol azeotropic system by virtue of the extracting agent, the single-tower operations are flexible, and the equipment cost is low.