The invention discloses an experimental device for testing a diffusion coefficient and an osmotic coefficient of an unsaturated dielectric gas. The device mainly comprises a gas-supplying device, a main body reaction device and an outlet gas processing device. The gas-supplying device comprises a water-bath heating device for heating transmitted gas, simulating the temperature generated by landfill refuse degradation and temperature variation generated by the external temperature change; the main body reaction device is composed of three parts of a lower chamber, a middle chamber and an upperchamber, which are used for simulating refuse landfill gas, landfill covering soil (or GCL) and soil sample upper environment. The upper part is loaded to a porous stainless steel plate through an aircylinder to apply pressure to a soil sample (or GCL), so as to simulate the soil pressure at the upper part of the landfill covering soil (or GCL). The outlet gas collecting device is mainly composedof a gas collecting bottle, can be used for collecting and treating the gas after reaction, and the situation that the gas after experiment pollutes the air is avoided. The device is simple in structure and wide in application range.