The invention belongs to the technical field of pollutant monitoring, early warning and tracing system construction methods, in particular to a refinery enterprise atmospheric pollutant monitoring, early warning and traceability system construction method. The refinery enterprise atmospheric pollutant monitoring, early warning and traceability system construction method comprises the following steps of: S1, enterprise environmental risk assessment; S2, monitoring station construction, specifically, based on monitoring factors and risk units determined in the step S1, carrying out monitoring point position arrangement and monitoring instrument selection to form a pollutant monitoring system in which a plurality of monitoring instruments are jointly applied; and S3, tracing and early warninginformatization platform construction. According to the refinery enterprise atmospheric pollutant monitoring, early warning and tracing system construction method provided by the invention, monitoring factors capable of representing refinery enterprise pollution characteristics are selected; by means of various high-sensitivity devices, a production unit fingerprint spectrum technology and a pollutant source analysis technology, an omnibearing atmospheric pollutant monitoring, early warning and tracing system is formed, and a novel pollution prevention and treatment mode for refinery enterprises is established.