The invention relates to a frequency selective surface structure with wide passband and ultra-wide stopband. The frequency selective surface structure comprises a fine square ring array layer, a spiral meander line array layer and a thick square ring array layer, wherein the fine square ring array layer is etched on an upper surface inner side dielectric plate, the spiral meander line array layer is etched on an intermediate metal layer lower side dielectric plate, the thick square ring array layer is etched on a lower surface outer side dielectric plate, an upper side foam material interlayer is further arranged between the upper surface inner side dielectric plate and the intermediate metal layer lower side dielectric plate, and a lower side foam material interlayer is further arranged between the intermediate metal layer lower side dielectric plate and the lower surface outer side dielectric plate. The frequency selective surface structure has the advantages of small unit size, small thickness, low transmission loss, wide passband, good out-of-band rejection, further has the beneficial effects of ultra-wide stopband, wide electromagnetic wave scanning angular domain and stable scanning along azimuth angle of frequency response, and can be widely applied to antenna housing design in platforms such as radars, satellite communication and aircrafts.