The invention relates to a method for determining the copolymerization proportion of
fluorinated ethylene propylene by using a quantitative high-resolution
solid nuclear magnetic resonance 19F MAS method, and relates to the technical field of
fluorine chemical industry. The method mainly comprises the following steps: firstly, completing spectrum peak affiliation of a 19F spectrum of FEP through a one-dimensional high-resolution
solid nuclear magnetic resonance 19F MAS experiment, determining characteristic peaks respectively representing FEP copolymerization units
tetrafluoroethylene (TFE) and
hexafluoropropylene (HFP), and then completing measurement of 19F
atomic nucleus spin lattice relaxation time T1 of a series of FEP samples with different melting points, so as to determine key test conditions for quantifying SS NMR 19F MAS. Finally, the FEP copolymerization proportion is calculated, and the scientific relation between the
mass fraction of the HFP in the FEP and the
melting point of the HFP is determined, so that after the
melting point data of the sample is obtained, the
mass fraction of the HFP in the sample can be calculated through the
linear relation formula of the obtained
melting point and the
mass fraction of the HFP in the FEP without
solid nuclear magnetic characterization, and the calculation accuracy of the
mass fraction of the HFP in the sample is improved. Therefore, the characterization efficiency of the indissolvable and infusible perfluorocopolymer in actual scientific research or production can be improved.