The invention discloses a metal-CO2 battery. The metal-CO2 battery comprises a positive electrode, a negative electrode, an organic electrolyte and a separator, wherein the positive electrode is an IrO2/MnO2 composite electrode with a hierarchical structure, comprises sheet-shaped MnO2 and also comprises nanometer IrO2 particles, the sheet-shaped MnO2 is directly grown on a substrate, strip-shaped MnO2 also covers a surface of the sheet-shaped MnO2, the nanometer IrO2 particles are uniformly loaded on the surfaces of the sheet-shaped MnO2 and the strip-shaped MnO2, and the negative electrode is selected from an alkali metal electrode subjected to surface protection processing. The invention discloses the metal-CO2 battery, the IrO2/MnO2 composite electrode with the hierarchical structure is used as the positive electrode, the alkali metal electrode subjected to surface projection processing is used as the negative electrode, electric energy is generated by greenhouse gas CO2, and the metal-CO2 battery obtained by assembly shows low polarization, high capacity and long cycle lifetime.