The invention discloses a magnetic coupling resonant wireless electric energy transmission device based on a low frequency PWM rectifier. The device comprises a rectifier, a voltage stabilizing capacitor, an inverter power switch, an emission circuit resonant capacitor, an emission circuit resonant coil, an emission circuit current sampling resistor, a receiving circuit resonant coil, a receiving circuit current sampling resistor, a rectifier power switch, a resonant filter capacitor, a resonant filter inductor, a load resistor, a transmitting end signal conditioning circuit, a transmitting end analog to digital converter, a transmitting end microprocessor, a transmitting end high frequency inverter driving circuit, an induction voltage detection coil, a receiving end signal conditioning circuit, a receiving end analog to digital converter, a receiving end microprocessor and a PWM rectifier driving circuit. According to the device, the resonance of an emission loop is ensured, the tracking of transmitting end working frequency, the resonance of a receiving circuit and the constant output of load voltage are realized, the requirement of working frequency by a power switch device is greatly reduced, and a space is provided for the device to raise power supply working frequency.