The invention discloses a high-sensitive third harmonic voltage differential stator grounding protection method, comprising the following steps: acquiring Un (k), Us (k), UA (k), UB (k), UC (k); Calculated as shown in the descrption; calculate. DELTA U3n (t) and. DELTA U3s (t); According to deltaU 3n (t) and deltaU 3s (t), it is judged whether the zero-sequence voltage of the generator is broken or not, and the protection is blocked if the generator is broken. U3d, U3r, U3d 'and U3r' were calculated. When the zero-sequence voltage of the generator is not broken, whether the operation conditionis satisfied or not is judged according to U3d, U3r, U3d 'and U3r'. If yes, the protection operation is delayed. The invention has the beneficial effects that the insulation of the stator winding tothe ground is reduced slowly, the zero-sequence voltage loop of the generator is broken without misoperation, and the reliability of the generator is improved.