The invention provides a large high-accuracy gear composite grinding center. An outer tooth grinding function module is arranged on the right of a rotation work table and comprises a tool body, a column, a grinding wheel frame, a grinding wheel dressing unit, an outer tooth grinding unit and an on-machine measuring unit. An inner tooth, inner hole and end grinding function module is arranged on the left of the rotation work table and comprises a tool body, a column, an inner hole and end grinding unit and an inner tooth grinding unit. By means of the grinding center, one-step clamping of large gears is achieved, the tooth face, inner hole and end grinding and accuracy detection are completed; the problems that large gears are difficult to hoist, clamp, correct and detect, the machining cost is high, the production efficiency is low, the accuracy is hard to guarantee are solved; assisting time among processes is shortened greatly, the number of tools and clamps is reduced, the machining period is shortened, the operation area is saved, the economic benefit is improved apparently, and the traditional machining mode of large gear production through a plurality of large tools and gear measuring instruments is changed completely.