The invention aims to provide a composite bending steel pipe lined with integrated ceramic and preparation technology thereof. The steel pipe adopts the following formula: 70 to 90 percent of alumina, 3 to 7 percent of barium carbonate, 3 to 5 percent of crystal whisker, 1 to 8 percent of talcum, 1 to 5 percent of Suzhou clay, and 2 to 5 percent of chromium oxide. Working procedures such as material distribution, ball milling, squeezing, vacuum pugging, molding, sintering and compounding can be adopted. The wear resistance of the composite bending steel pipe is 5 to 6 times of that of a patch ceramic bending pipe and is 10 to 20 times of that of a high-chromium cast iron bending steel pipe, the wear loss is less than or equal to 0.015 percent, the water absorbing capacity is less than 0.02 percent, the Mohs hardness is between 8 and 9, and the composite bending steel pipe can bear the high temperature of 800 DEG C for a long time, is acid-resistant and alkali-resistant, and has the service life of between 12 and 18 years.