The invention discloses an organic network preparation method of ferrozirconium red zirconia nano-
composite ceramic powder. The organic network preparation method comprises the following steps: mixing 
polyvinyl alcohol with water, heating, stirring, standing, and cooling to the 
room temperature, so as to obtain an organic network precursor solution; sequentially adding 
zirconium oxychloride, iron 
nitrate nonahydrate, silica 
sol and 
glutaraldehyde while stirring so as to generate Zr<4+> and coloration 
ion / organic network gel; after standing, soaking in 
ammonia water, washing with deionized water until the mixture is neutral, and 
drying and crushing to generate dry gel 
powder; calcining so as to obtain the ferrozirconium red zirconia nano-
composite ceramic powder. According to the organic network preparation method, 
ceramic colorant pigments and 
zirconia ceramic powder are mixed at nano scale, the uniform degree of the mixture of the pigments and the 
ceramic raw material powder is greatly increased, the 
sintering temperature of composite powder is decreased, sintered red 
zirconia ceramic is high in strength and good in color generation, and the influences of carbon residues generated after the 
combustion of organic matters on the purity of the ferrozirconium red zirconia powder are reduced.