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Sludge charcoal for repairing heavy metal contaminated soil and preparation method of sludge charcoal

The invention belongs to the technical field of in-situ repair of heavy metal contaminated soil. Municipal sludge is used for preparing sludge-based charcoal through thermophilic thermolysis. The charcoal can be used as a repairing agent for the heavy metal contaminated soil. The sludge charcoal repairing agent comprises thickened sludge and palygorskite. A final black product namely the sludge-based charcoal is produced through the steps of performing biological and physical anhydration on sludge, then mixing the sludge after the biological and physical anhydration with the palygorskite, performing feeding into an atmosphere furnace, and then performing thermophilic thermolysis. The sludge charcoal is produced from the following components of 5-10% of the palygorskite and the balance of thethickened sludge. According to the sludge charcoal disclosed by the invention, the municipal sludge is subjected to decrement and harmless treatment, so that the municipal sludge can enter cycle of material and energy in natural environment again, and the difficult problem of treating and disposing the sludge is solved. The sludge charcoal is added to the heavy metal contaminated soil, so that heavy metal contaminated substances can be effectively solidified, the purposes of being durable and stable in repairing effect and being free from secondary pollution are realized, and the sludge charcoal is an ideal soil heavy metal contamination repairing agent with low cost.
Owner:LANZHOU JIAOTONG UNIV

Method for preparing in-situ passivation restoring material of soil heavy metal with copolycondensation method

The invention relates to a method for preparing an in-situ passivation restoring material of soil heavy metal with a copolycondensation method. A cellular material with high specific surface area is prepared by using a mesoporous silicon dioxide SiO2 as the base material and introducing sulfydryl having strong bonding fixation ability with a heavy metal ion via surface modification. The preparation method comprises the following steps: (1) mixing water with methanol; (2) adding templates of hexadecyl trimethyl ammonium bromide and sodium hydroxide; (3) using methyl orthosilicate and mercapto-propyl trimethoxy silane as a silicon source; (4) continuously stirring the mixed solution for 12h; (5) heating the solution in water at a constant temperature of 96 DEG C; (6) obtaining white powder by filtering, collecting and air drying; and (7) transferring the mixture into a soxhlet extractor to be extracted by ethanol, collecting samples for air drying and performing vacuum drying at 80 DEG Cto obtain the finished product. The invention has the advantages of simple process, low cost, high restoring efficiency, no secondary pollution and safe use, and is suitable for large-scale promotionand application.
Owner:AGRO ENVIRONMENTAL PROTECTION INST OF MIN OF AGRI

Passivation material for in-situ restoration of soil polluted by heavy metal, and preparation and use method thereof

The invention relates to a technique for treating and restoring soil polluted by heavy metal, in particular to a passivation material for in-situ restoration of soil polluted by heavy metal and a usemethod thereof. The material can be prepared by the following steps: mixing tetramethylammonium hydroxide, cetyl trimethyl ammonium bromide, ethyl orthosilicate and water for reaction according to a mole ratio of (0.3-0.4): (0.2-0.3): 1:(100-120) to obtain a gel, placing the gel for 24 hours at a room temperature, filtering and washing solid product for many times, drying at 100-140 DEG C for 2-4hours and then baking at 500-600 DEG C for 4-8 hours to obtain the finished product. The passivation material can be applied into soil according to a proportion of 0.45-0.9 percent of the weight of dry soil and evenly mixed according to the specific pollution condition of the soil. The passivation restoring material prepared in the invention has the advantages of simple production process, capability of fixing multiple heavy metals, favorable restoring effect, wide application range, and the like, has little user amount, does not influence the physiochemical property of soil and can not causesecondary pollution.
Owner:AGRO ENVIRONMENTAL PROTECTION INST OF MIN OF AGRI
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