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156 results about "Lithium disilicate" patented technology

Glass ceramics are categorized according to their major crystalline structure and/or application. 2 Lithium disilicate is among the best known and most widely used types of glass ceramics. The IPS e. max lithium disilicate, for example, is composed of quartz, lithium dioxide, phosphor oxide, alumina, potassium oxide, and other components.

Lithium disilicate glass-ceramics composite material using ZrO2 as reinforcing phase and method for making same

InactiveCN101139170AGuaranteed densificationGood mechanical propertiesGlass particleMechanical property
The present invention relates to a lithium disilicate glass-ceramic composite material with ZrO2 as the reinforcing phase and thepreparation method, which solve the problems that the production cycle is long, the cost is high, the products can be easily formed and the mechanical properties of the lithium disilicate glass-ceramic is lower. The present invention is composed of the lithium disilicate base glass and zirconia powders. The preparation method goes in that the ball milling is carried out according to the components of the original glass; the desiccated raw materials are placed in a corundum crucible so as to be melted under high temperature; the glass solution is poured into the distilled water to go into water quenching so as to be changed into 1 to 2mm glass particles; the ball milling is applied to the glass particles after going into the water quenching so as to obtain the glass powders; the lithium disilicate glass powder is taken to be mixed with the zirconia powders and the ball milling is applied to the lithium disilicate glass powder and the zirconia powders with the alcohol as the medium; the vacuum heating-press sintering is implemented and then the lithium disilicate glass-ceramic composite material with ZrO2 as the reinforcing phase is prepared. The present invention is uneasily deformed, has short production cycle and low cost and has excellent bending strength and fracture toughness indexes.
Owner:HARBIN INST OF TECH

Rare earth-mixing high strength lithium bisilicate sitall material and preparation method thereof

The invention relates to a rare earth-mixing high strength lithium bisilicate sitall material and a preparation method thereof. Parent glass of the invention includes the following components according to molar percentage: 61.2 to 66.0 percent of SiO2, 0 to 2.5 percent of B2O3, 0 to 1.6 percent of Al2O3, 1.0 to 3.7 percent of P2O5, 0 to 2.3 percent of ZrO2, 1.0 to 1.8 percent of K2O, 24.2 to 31.8 percent of Li2O, 0 to 2.0 percent of MgO, 0 to 2.0 percent of CaO, and 0.5 to 4.2 percent of La2O3+Y2O3. A corresponding raw material prepared from the oxidates is processed by the steps of ball milling, 80 mesh sieve sieving and uniform mixing to obtain a batch; the batch is led into a copple to be melted after the temperature from 1480 to 1520 DEG C is maintained for 2 to 3 hours, and the melted batch is cast into a stainless steel mould to be molded and then is annealed at 500 DEG C for 0.5 hour; and the step of coring is carried out in a resistance furnace at the temperature from 500 to 550 DEG C for 1 hour, and the step of crystallization is carried out at the temperature from 600 to 850 DEG C for 2 hours. The crystallization degree of the sitall is as high as 60 to 70 percent, the flexural strength is 100 MPa or more higher than the sitall to which the rare earth oxides are not added, the highest flexural strength reaches 334 MPa, the maximum elastic modulus reaches 143 GPa, and the highest fracture toughness reaches 3.34 MPa-m. The sitall of the invention has favorable stability, and the heat treatment temperature is lower and is easy to control.
Owner:CENT SOUTH UNIV

Method for molding dental restorations and related apparatus

InactiveUS20050115460A1Readily molded into dental restorationEasy to useImpression capsOther chemical processesWorking temperatureDental restoration
The present invention is concerned with a process for the formation of dental restorations from glass-ceramic materials, and the resulting dental restorations. In this invention, a dental restoration is prepared by placing a glass-ceramic material in a heat-pressure deformable crucible. Heat is then applied to the crucible in order to bring the glass-ceramic material to working range at temperatures above its liquidus temperature. The crucible in which the glass-ceramic material is placed has heat-pressure deformation properties which are matched to the working temperature of the glass-ceramic material being heated. The heat deformation properties of the crucible must be such that when the glass-ceramic material in the crucible is in the working range, the crucible is heat-pressure deformable without rupturing. Once the glass-ceramic material is heated to its working temperature, the crucible is brought into contact with a mold having a preformed cavity therein, the cavity being in the shape of the desired dental restoration. As the distance between the heated glass-ceramic material and the mold is decreased, the crucible is deformed to form a seal with the mold, thereby facilitating the injection of the molten glass-ceramic material into the mold cavity. An interactive seal between the crucible and the mold may be provided for. The composite process may be carried out in a vacuum. The resulting dental restoration has superior optical esthetic and strength properties. The invention further includes the heat-pressure deformable crucible. The invention includes dental restorations which are formed from particular lithium-disilicate glass-ceramics. In addition to forming dental restorations by the process of this invention, the dental restorations may be milled.
Owner:PETTICREW RICHARD W

Lithium silicate microcrystalline glass and lithium disilicate microcrystalline glass with high permeability, and preparation method and application thereof

The invention relates to a lithium silicate microcrystalline glass and a lithium disilicate microcrystalline glass with high permeability, and a preparation method and application thereof. The size oflithium silicate crystal in the lithium silicate microcrystalline glass is smaller than 50nm; the size of lithium disilicate crystal in the lithium disilicate microcrystalline glass is smaller than 200nm. The lithium silicate microcrystalline glass and the lithium disilicate microcrystalline glass have the advantages that the basic glass is prepared by the particular combination, a cooperation relationship among SiO2 (silicon dioxide), Li2O (lithium dioxide) and other components is controlled, and a ratio relationship between SiO2 and Li2O is especially controlled; after primary heat treatment, the lithium silicate microcrystalline glass with size smaller than 50nm is obtained; after the lithium silicate microcrystalline glass is subject to heat treatment again, the lithium disilicate microcrystalline glass is prepared, the crystal size of the lithium disilicate microcrystalline glass is controlled to be 200nm or less, the light permeability is 20% to 95% at the wavelength of 550nm, the strength is 360MPa to 450MPa, and the clinical requirement of the high permeability and excellent strength of the lithium disilicate microcrystalline glass can be met.
Owner:INST OF PROCESS ENG CHINESE ACAD OF SCI

Lithium disilicate glass ceramic used for dental zirconia veneering porcelain and preparation method and application thereof

The invention discloses a lithium disilicate glass ceramic used for dental zirconia veneering porcelain and a preparation method and application thereof, the lithium disilicate glass ceramic comprises56%-58% of SiO2, 27%-29% of Li2CO3, 3.7%-3.8% of K2CO3, 2.7%-2.8% of Al2O3, 2.3%-2.4% of ZrO2, 2.5%-2.6% of P2O5, 2.2%-3.8% of B2O3, 0.5% of Ti2O and 0.5% of CeO2. The preparation method comprises the steps that after raw material ball-milling and mixing, melting is performed, a melt is obtained, the melt is poured into a mold, then annealing is performed, and a glass blank is obtained; the glassblank is subjected to crystallization heat treatment, and the lithium disilicate glass ceramic is obtained. The obtained lithium disilicate glass ceramic is high in flexural strength, and the damageprobability of a restoration body due to veneering porcelain cracking can be remarkably reduced. The invention provides a method applying the lithium disilicate glass ceramic as zirconia veneering porcelain, in the restoration body obtained with the method, the bonding strength of the lithium disilicate glass ceramic veneering porcelain with a zirconia substrate is far higher than that of traditional zirconia decoration ceramic porcelain with the zirconia substrate, and the cracking resistance of a zirconia all-ceramic restoration body can be improved remarkably and the service life can be prolonged.
Owner:FOURTH MILITARY MEDICAL UNIVERSITY

Glass ceramic with high elasticity modulus, and reinforced glass ceramic and preparation method thereof

The invention provides a glass ceramic with high elasticity modulus. The principal crystalline phase of the glass ceramic is composed of at least two selected from the group consisting of lithium silicate, lithium disilicate, petalite and ZrO2. The glass ceramic comprises 18%-30% of Li2O in molar percentage, and the crystal size of the glass ceramic is 10-80 nm; the elastic modulus of the glass ceramic is at least 90 Gpa. The glass ceramic comprises the following components in percentage by mol: 55-70% of SiO2, 3-10% of Al2O3, 1-6% of P2O5, 0.5-5% of ZrO2, 0.5-5% of Na2O, 18-30% of Li2O and 0-3% of Ta2O5. The glass ceramic further comprises at least one of the following oxides: 0 to 0.5% of CeO2, 0 to 0.5% of SnO2, 0 to 5% of B2O3, 0 to 5% of ZnO and 0 to 5% of MgO. The invention relates to the glass ceramic with high Li content; the network structure of the glass ceramic is compact; the obtained principal crystalline phase is composed of lithium disilicate and a beta quartz solid solution; due to the high crystallization ratio and crystal type of the glass ceramic, a material with elasticity modulus higher than 90 Gpa can be obtained; and a glass ceramic material with visible light transmittance higher than 90% can be obtained by controlling the crystal size, and the glass ceramic material can be used for window materials of aviation airplanes, high-speed rails, subways, carsand the like.
Owner:CHONGQING XINJING SPECIAL GLASS CO LTD

High-strength bacteriostatic antibacterial lithium disilicate glass ceramic and preparation method thereof

High-strength bacteriostatic antibacterial lithium disilicate glass ceramic and a preparation method thereof belong to the technical field of biological materials. In the prior art, a dental department all-ceramic restorative material obtained by doping Ag<+>, Zn<2+> and Cu<2+> in lithium disilicate glass ceramic does not exist. The high-strength bacteriostatic antibacterial lithium disilicate glass ceramic is characterized by preparing materials for matrix glass according to the weight percentage of the matrix glass, additionally determining the total weight of Ag2O, ZnO and CuO in the high-strength bacteriostatic antibacterial lithium disilicate glass ceramic according to the ratio of 0.1 to 8 percent of the weight of the matrix glass, and preparing the matrix glass by adopting a high temperature melting method, wherein the content of the Ag2O is larger than or equal to 0 percent but less than or equal to 2 percent, ZnO is larger than or equal to 0 percent but less than or equal to 5 percent and CuO is larger than or equal to 0 percent but less than or equal to 1 percent, wherein only the content of AgO2, ZnO and CuO is allowed to be equal to 0 at the same time; coring the prepared matrix glass at the temperature of 450 to 550 DEG C for 1.5 to 2.5 hours; performing three-step crystallization: crystallizing at the temperature of 650 to 680 DEG C for 1 to 3 hours, crystallizing at the temperature of 710 to 740 DEG C for 20 to 60 minutes, crystallizing at the temperature of 800 to 830 DEG C for 10 to 20 minutes, so as to obtain the high-strength bacteriostatic antibacterial lithium disilicate glass ceramic.
Owner:CHANGCHUN UNIV OF SCI & TECH

Lithium disilicate microcrystalline glass material prepared by using hybrid reaction sintering method and method

ActiveCN103553339AGuaranteed densificationImprove performanceLithium metasilicateQuenching
The invention provides a lithium disilicate microcrystalline glass material prepared by using a hybrid reaction sintering method and the method. Raw materials for the material comprise lithium metasilicate crystal powder M, quartz sand glass powder S and lithium disilicate basic glass powder D, wherein a mol ratio of M to S to D is 1: 1-2: 0-8. The method comprises the following steps: subjecting lithium metasilicate glass and lithium disilicate basic glass to melting, water quenching and ball milling so as to prepare glass powder; subjecting lithium metasilicate glass powder to crystallization to obtain a crystal; adding the quartz sand glass powder and the lithium disilicate basic glass powder D; and uniformly mixing the above-mentioned three powders and carrying out sintering in a vacuum hot-pressing furnace so as to prepare lithium disilicate microcrystalline glass. The lithium disilicate microcrystalline glass produced by using the method has bending strength of 255 to 420 MPa and fracture toughness of 2.6 MPa.m1/2 to 3.5 MPa.m1/2. Compared with the prior art, the invention has the following advantages: production cost is reduced; desired pigments can be added into the mixed powder before sintering, which enables the problem of difficult color matching in a melting method to be overcome; a long rod-like crystal grain with length 5 times the size of a single glass powder sintered body is prepared; and a novel approach is opened up for toughening the lithium disilicate microcrystalline glass.
Owner:XI AN JIAOTONG UNIV
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