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35 results about "ORGANIC IODIDE" patented technology

Organic Iodide Powder is to be used as a nutritional source of iodine. Add to ration (protein, grain, or salt mix) in proportions to provide 10 mg per head per day. Protein Mix: Add 1/2 lb per ton of protein mix and feed at a rate of not more than 2 lbs of mix per head per day. Grain Mix: Add 1 oz ...

Wet recycling process for impregnated active carbon by extraction with organic solvent

A wet recycling method for impregnated active carbon used to remove radioactive organic iodide in a nuclear power plant by extracting impregnated substance and radioactive organic iodide from the used impregnated active carbon with an acetonitrile solution and reproducing active carbon to be used in preparing impregnated active carbon, the filtered extractive solution being distilled to obtain pure acetonitrile for the use purpose as an extractive solution, the impregnated substance and radioactive organic iodide extracted in a small amount of solid, thus reducing the volume of the waste impregnated active carbon greatly to decrease solid waste material and at the same time recycle materials.
Owner:KOREA ATOMIC ENERGY RES INST

Zeolite deiodination adsorbent with high silver carrying amount and its prepn process

The preent invention is zeolite deiodination adsorbent with high silver carrying amount for eliminating iodide in acetic acid and its preparation process. The adsorbent is superior to available ones, which are high in cost and have complicated production process. The adsorbent of the present invention is prepared with one kind of natural mineral ziolite, named stilbite, and through denaturing and cationic exchange. It has silver carrying amount up to 26%, and may be used in eliminating organic iodide, inorganic iodide and molecular iodine.
Owner:FUDAN UNIV +1

Preparation method of high silver carrying ZSM-5 zeolite deiodine adsorbing agent

A process for preparing the ZSM-5 zeolite adsorbing containing more carried silver (20%) for removing iodide from acetic acid includes such steps as pulverizing H-ZSM-5 zeolite with the ratio of SiO2 / Al2O3=15-30, adhering for shaping, crystallizing, and silver ion exchange.
Owner:SHANGHAI WUJING CHEM +1

High silver supported zeolite molecular sieve acetate deiodinase adsorber and preparation method thereof

The invention belongs to the chemical technical field and relates to a high silver supported zeolite molecular sieve acetate deiodinase adsorber and a preparation method thereof. In the adsorber, the sizes of zeolite cavity openings are respectively 0.66*0.71 nanometers and 0.56*0.56 nanometers, and the adsorber is provided with characteristic X-ray diffraction lines in a BEA (Background Equivalent Activity) type zeolite structure. The deiodinase adsorber is prepared by the steps that saled sodium type zeolite molecular sieve powder with two-dimensional twelve oygen membered ring cavity openings is formed through binder, is in in-situ hydrothermal strengthening treatment to generate chemical bonds and then is treated by ion exchange sodium removal and silver carrying. The adsorber has the advantages of high crystallization degree, strong particle strength, high silver supported and strong adsorption capacity to organic iodide, inorganic iodide and molecular iodide with different sizes contained in strong acidic medium, can enable the total iodide content in product acetic acid after deiodination treatment by the adsorber to be lower than 5ppb and is suitable for being used as raw materials for synthetizing vinyl acetate.
Owner:FUDAN UNIV +1

Preparation method, product and applications thereof of acetate deep deiodination adsorbent

The invention relates to preparation method, product and applications thereof of an acetate deep deiodination adsorbent. The method comprises the following steps of: mixing small-pore, medium-pore and large-pore zeolite molecular sieves with different structures; forming by using an adhesive; generating chemical bonds by hydrothermal strengthening treatment; removing sodium and loading silver by ion exchange to prepare the product. The adsorbent is prepared from the following components in percentage by weight: 10-30% of small-pore zeolite, 20-50% of medium-pore zeolite and 20-70% of large-pore zeolite, and the adhesive accounts for 10-30% of the total weight of the adsorbent. The invention has the advantage that the adsorbent has strong adsorption capability on organic iodide, inorganic iodide and molecular iodine with different sizes in the strong acid medium, the total iodine content in the deep deiodination product is less than 5*10<-9>, and the adsorbent is suitable for being used as raw materials which are used for synthesizing vinyl acetate.
Owner:SHANGHAI FUXU MOLECULAR SIEVE

Macroporous zeolite absorbent and preparation method thereof

The invention provides the large aperture zeolitic adsorbent and preparing method. The method comprises the following steps: hydrothermal synthesizing the zeolitic in Na2O-SiO2-Al2O3-H2O colloidal system, possessing the X-ray spectrum, removing the sodium with positive ion exchange, forming with binding agent and modifying with aqueous vapor. The average pore size of adsorbent is 11 nanometers, and the adsorbent is used to remove micro inorganic or organic iodide and iodine from acid medium.
Owner:FUDAN UNIV +1

No-adhesive zeolite adsorbent for organic liquid medium iodine removing method

The organic liquid medium deiodinating process with no-adhesive zeolite adsorbent includes: filling no-adhesive zeolite adsorbent in fixed bed, making the iodine-containing medium contact with no-adhesive zeolite adsorbent containing at least one kind of exchanging metal cation, controlling the temperature and space velocity of the organic liquid medium passing through the adsorbing bed to lower the total iodine content in the iodine containing medium to less than 10 ppb. The adsorbent is prepared with hydrogen type zeolite powder with SiO2 / Al2O3 ratio of 15-30 and through adhering to form and crystal conversion. The adsorbent can eliminate organic and inorganic iodide and molecular iodine from organic medium effectively. The method of the present invention is suitable for eliminating iodide from various organic matters.
Owner:SHANGHAI WUJING CHEM +1

Electrolyte for dye sensitized solar cells

The invention discloses an electrolyte for dye sensitized solar cells. The electrolyte comprises organic iodide, elementary iodine, additive and solvent, wherein the organic iodide is prepared through reaction of 1-alkyl substituted imidazole and 2-alkyl iodides. The electrolyte has stable physical and chemical properties and low cost and can be used for replacing lithium iodide which is high in price and bad in stability. By using the electrolyte provided, the stability of the dye sensitized solar cells can be improved, the cost is reduced, and benefit is brought to the industrialized application of the cells.
Owner:WUHAN UNIV

Acid resistant zeolite adsorbent and preparation thereof

An acid-resistant zeolite adsorbent with characteristic X-ray diffraction spectrum is prepared through hydrothermal synthesizing of zeolite in Na2O-SiO2-Al2O3-H2O colloidal reactant system, cationic exchanging for removing Na, adding adhesive, shaping and steam ageing. Its advantages are high resistance to acid, high strength and uniform pore structure.
Owner:FUDAN UNIV +1

Method for removing iodine and iodine compound impurity

The method of removing iodine and iodide impurity features that the medium containing iodide is made to contact with one kind of adsorbent to eliminate its iodide. The adsorbent is prepared with natural mineral zeolite, such as STI, and through modification and cation exchange. The adsorbent is stable in the medium to be processed and can eliminate organic and inorganic iodide and molecular iodine from the medium effectively. The adsorption conditions include temperature of 18-100 deg.c, and liquid space velocity of 1-20 / hr and the processed liquid has total iodine content less than 10 ppb.
Owner:SHANGHAI WUJING CHEM +1

Metal-Organic Framework Based Molecular Traps for Capture of Radioactive Organic Iodides from Nuclear Waste

Novel radioactive iodide molecular traps, in which one or more metal atoms are functionalized by coordinating to an amine containing two or more nitrogens, and methods of using the molecular traps to capture radioactive iodide.
Owner:RUTGERS THE STATE UNIV

Polyamide resin, and preparation method therefor and molded product thereof

ActiveCN105440281AFiberORGANIC IODIDE
The present invention relates to polyamide resin that contains an non-ionic organic iodide, and has excellent long-time melting retention stability. The present invention relates to polyamide resin that contains a diamine unit and a dicarboxylic acid unit with 50-100 mol% being an oxalic acid unit, and the polyamide resin contains the non-ionic organic iodide, and with respect to the weight of the polyamide resin, the iodine content is 20-6000 ppm. The polyamide resin has excellent processability. The polyamide resin can be used in resin molded products, fiber, films and the like in automobile parts, mechanical parts and the like.
Owner:TORAY ADVANCED MATERIALS RES LAB CHINA

Acetylthiocholine iodide as well as preparation method and application thereof

The invention provides acetylthiocholine iodide and a preparation method thereof. The preparation method comprises the following steps: step S1, dissolving a dimethylamino ethane compound in alkali toobtain an alkaline aqueous solution; step S2, adding a thioacetic acid compound into the alkaline aqueous solution to subject the thioacetic acid compound and the dimethylamino ethane compound to a thioreaction to generate (2-(dimethylamino)ethyl)ethanethioate; S3, separating the (2-(dimethylamino)ethyl)ethanethioate, and preparing an organic solution of the (2-(dimethylamino)ethyl)ethanethioate;and S4, dropwise adding an organic iodide into the organic solution of the (2-(dimethylamino)ethyl)ethanethioate for an iodination reaction so as to generate the acetylthiocholine iodide. According to the preparation method provided by the embodiment of the invention, the high-purity acetylthiocholine iodide can be obtained, and the titration content, the melting point, the clarity and other dataof the product are very excellent. The method is simple in operation, good in safety, suitable for industrial production, easy in raw material obtaining and low in cost.
Owner:安徽昊帆生物有限公司

Sorbent of zeolite with carrying silver, preparation method and application

The invention discloses a silver-bearing zeolite adsorbent, its preparation method and application. The invented silver-bearing zeolite adsorbent is a silver-bearing acid-resistant zeolite, its silver weight content is 7-15%. The described silver-bearing zeolite adsorbent can be used for removing trace iodide from acetic anhydride product. Besides, said invention also provides the concrete structure of said zeolite.
Owner:SHANGHAI HUAYI ENERGY CHEM +1

Sorbent of zeolite with carrying silver, preparation method and application thereof

The invention discloses a silver-loaded zeolite adsorbent, a preparation method and application thereof. The silver-loaded zeolite adsorbent of the present invention is a silver-loaded acid-resistant zeolite, and the weight content of the silver is 7-15%. The silver-loaded zeolite adsorbent can be used to remove trace amounts of iodide in acetic anhydride products. Said zeolite has structural pores of 10 oxygen member rings and 12 oxygen member rings, high strength, uniform distribution of coarse pores between zeolite crystal grains and good acid resistance. The zeolite is used as a substrate to carry silver to make an adsorbent of silver-carrying acid-resistant zeolite, which has high adsorption effect on iodide molecules of different molecular sizes, has high strength, high silver-carrying amount, and excellent pore distribution. The silver-loaded zeolite adsorbent of the present invention has a simple and convenient preparation method, can effectively remove inorganic and / or organic iodide and / or molecular iodine in the crude product of acetic anhydride, and has a high prospect of industrial implementation.
Owner:SHANGHAI HUAYI ENERGY CHEM +1

Preparation method of high silver carrying ZSM-5 zeolite deiodine adsorbing agent

The invention relates to a preparation method of a ZSM-5 zeolite adsorbent with high silver-loaded content used for removing iodide in acetic acid. The prior art has high cost, high price and complicated production operation process. Adsorbent of the present invention is made of SiO 2 / Al 2 o 3 The H-ZSM-5 zeolite powder with ≈15~30 is made by bonding molding, crystal transformation, and then exchanged with silver ions, and its maximum silver loading can reach 20%. The adsorbent can effectively remove organic iodide, inorganic iodide and molecular iodine in acetic acid.
Owner:SHANGHAI WUJING CHEM +1

Method for preparing in-situ silver-carried natural zeolite deiodinating adsorbent

The preparation method includes the following steps: breaking natural zeolite core into natural zeolite granules with 20-40 meshes, in-situ making ion exchange to obtain hydrogen-type natural zeolite, the using silver solt solution to make exchange so as to obtain deiodination adsorbing agent.
Owner:FUDAN UNIV +1

A method for synthesis of organic iodides, a perovskite-forming composition comprising an organic iodide and a photovoltaic cell with a perovskite layer obtained therefrom

A method for obtaining a salt with a general formula: RxNI, wherein: RxN is an organic cation (RxN+), R represents substituents (R-) independently selected from a group consisting of organic substituents: R1-, R2-, R3- and hydrogen (H-), x is a number of the substituents R- directly linked with the nitrogen (N) atom in the organic cation RxN+, wherein x is 3 or 4, I is an iodide anion (I-). The method comprises: preparing a reaction mixture comprising the steps of: synthesizing hydrogen iodide (HI) in situ by mixing molecular iodine (l2) with formic acid (COOH) in a molar ratio of molecular iodine (l2) : formic acid (COOH) of no less than 1.01:1, in a solvent medium, introducing into the solvent medium a compound being a donor of organic cation RxN+ in an amount providing the molar ratio of the donor of organic cation RxN+ : molecular iodine (l2) of no less than 1.01:1, and maintaining the reaction mixture at a temperature of not less than 20 DEG C for the time necessary to obtain the reaction product being the salt with the general formula RxNI. The obtained product is a substrate for synthesis of perovskites.
Owner:索尔股份公司

Base resistant fluorinated polymers

Disclosed herein are copolymers of tetrafluoroethylene and n-alkyl trifluorovinyl ether which further contain either curesite repeat units and / or iodine. Such curesite repeat units, upon exposure to free radicals, may crosslink the copolymers. The iodine is introduced by carrying out free radical polymerization in the presence of an organic iodide chain transfer agent. The polymers according to the invention are especially useful as elastomers and / or as molding resins for articles or parts that may be exposed to a basic environment. The preparation of such polymers by aqueous emulsion polymerization is also disclosed.
Owner:THE CHEMOURS CO FC LLC

Iodine transfer polymerization method and compositions therefrom

ActiveUS11390703B2Polymer scienceMeth-
Iodine transfer radical polymerization of an ethylenically unsaturated monomer comprising (meth)acrylic acid, salt thereof, or combination thereof, in the presence of a radical polymerization initiator, an organoiodide, and a solvent, is a useful method for making (meth)acrylic acid polymers. The amounts of components utilized can be 2 to 100 equivalents of acrylic acid and 2 to 100 equivalents of sodium acrylate, both dissolved in water to form a 15 to 50 weight percent solution, based on the total weight of the acrylic acid, sodium acrylate, and water; 0.05 to 1 equivalent of an azo polymerization initiator, 1 equivalent of an organoiodide; and 0 to 3 equivalents of an iodide salt. (Meth)acrylic acid polymer solutions are made by these methods. The (meth)acrylic polymers are useful as dispersants.
Owner:ROHM & HAAS CO +2
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