The invention discloses a skin-camouflaged ointment containing a base stock, stuffing, pigments and auxiliary agents; and with respect to each 100 parts of the ointment by weight, the parts of various components by weight are as follows: 58-62 parts of the base stock, 21-23 parts of the stuffing, 15-16 parts of the pigments and 1.5-2.0 parts of the auxiliary agents. A preparation method of the skin-camouflaged ointment comprises the following steps of: carrying out fine grinding on the stuffing to obtain the fineness of more than 800 meshes; mixing the finely ground stuffing with the base stock, the pigments and the auxiliary agents at 60-70 DEG C and sufficiently stirring for 25-35 min; and cooling to the room temperature to obtain the prepared ointment. When the skin-camouflaged ointment is used, according to the relevant requirements of camouflage painting, skin-camouflaged ointments with different colors are coated on the exposed skins such as faces, necks and hands of people so as to inhibit reflection and infrared radiation features of the skins, change original outline shapes of the faces of people, effectively integrate with color patterns and near infrared landscapes of the background, thereby improving the survivability of people in battlefield. The ointment disclosed by the invention has good water resistance, air permeability, weather resistance, and skin-moisturizing performance; and the ointment is easy to wipe off, has no smell and good skin compatibility, and is applicable to camouflage painting of skins of people during training exercises and battles and also applicable to body painting or personalized skin coating decorations.