The invention discloses lead acid storage battery positive electrode lead paste and a preparation method thereof. The lead acid storage battery positive electrode lead paste is prepared from the following ingredients in parts by weight: 70 to 90 parts of lead powder, 0.01 to 0.1 part of adhesive-free carbon fiber, 0.01 to 0.1 part of basalt fiber, 0 to 0.8 part of 4BS seed crystals, 5 to 12 parts of lead tetraoxide, 2 to 8 parts of antimonous oxide, 1 to 5 parts of polyester fiber, 2 to 6 parts of triniobium aluminum, 2 to 7 parts of sulfuric acid, 6 to 8 parts of hydrosulfate,3 to 6 parts of nanometer silicon dioxide, 15 to 20 parts of nucleocapsid acrylic acid elastic emulsion, 0.5 to 1.5 parts of carboxymethyl cellulose, 0.35 to 1.05 parts of chemical-resistant modifying agents and 9 to 13 parts of pure water. The adhesive-free carbon fiber addition technology is used, and the adhesive-free carbon fiber can enhance the adhesion effect of the lead paste; in addition, the lead paste low-acid content technology is used, so that the battery deep circulation service life is greatly prolonged; through the addition of the nucleocapsid acrylic acid elastic emulsion and the nanometer silicon dioxide, the weathering performance of the lead paste is improved; the perfluoroalkyl acrylic acid series additives are introduced to be used as chemical-resistant modifying agents, so that the anti-corrosion performance of the lead paste is greatly improved.