The system for carrying out monitoring operation status of power substation in real time includes following parts: CPU, modules including safe operations, production run, marketing operations, professional operations, and synthesis operations. All the said modules are connected to CPU. The professional operation module includes voltage no-load operation module, module for running at voltage monitor point, operation module for power supply reliability target, operation module for scheduled outage, operation module for temporary outage, operation module for accident outage, and operation module of line loss. Comparing with prior art, the invention overcomes disadvantages: difficult to collect data, issuing result out of time, low efficiency for operating service, poor reliability of power service, deviation and mistake appearing easily, and even creating accident.