The invention belongs to the technical field of environmental
analytical chemistry, and particularly relates to a method for simply and accurately analyzing
ion states and particle states of
metal nanoparticles in a
water body. The method comprises the steps of
electron microscope coupling energy spectrum identification,
ion state separation and extraction through a filter membrane, acidolysis of the
ion state and the mixed state,
microwave digestion, acid removal and constant volume and quantitative detection and analysis, meanwhile, a sample
pretreatment method for digesting
titanium dioxide and
zinc oxide through
hydrofluoric acid is abandoned, and operation is
safer. The method provided by the invention overcomes the dependence and limitation of advanced instruments such as spICP-MS and the like, reduces the test and analysis cost, overcomes the error caused by conversion of
particle number concentration and ion
mass concentration, and meets the requirement on
water sample particle homogenization. Meanwhile, a simple, accurate and high-
recovery-
rate analysis method is innovatively formed on the basis of existing equipment, the
bottleneck that the ionic state and the particle state are difficult to quantitatively compare is overcome, the deficiency of a
nanoparticle biological quantitative
standardization process is made up, and the method has good generalization performance.