The invention discloses a measuring and calculating method for the electronic thermal conductivity of a metallic nano-mesoporous material. The method comprises the steps that the size and shape of the metallic nano-mesoporous material to be detected and the electron mean free path l[0B] of an existing block material corresponding to the metallic block material are determined; 2, the electron free path l[00] of the metallic block material is determined; 3, an electron is randomly selected from the metallic nano-mesoporous material; 4, the free path of the current selected metallic nano-mesoporous material electron is determined; 5, the mean free path l[0] of all the electrons is calculated when the current selected electron completes motion; 6, the electron mean free path l is output; 7, the electronic thermal conductivity k of the metallic nano-mesoporous material is calculated. According to the method, the electronic thermal conductivity of the metallic nano-mesoporous material can be measured and calculated, the electronic thermal conductivity of the nano-mesoporous material can be conveniently obtained when the electronic thermal conductivity cannot be directly measured, and subsequent research on the thermal transmission characteristics of the metallic nano-mesoporous material is promoted.