140results about "Calcium organic compounds" patented technology

The invention provides a coordination polymer material with a multistage pore passage structure and a preparation method thereof. The coordination polymer material with a multistage pore passage structure is internally provided with the multistage pore passage structure, the multistage pore passage structure is a microporous and / or mesoporous and / or macroporous multistage pore passage structure which is formed by the self assembly between the metal ion and the organic ligand, the apertures of the micropores are less than or equal to 2nm, the apertures of the mesopores are from 2nm to 50nm, and the apertures of the macropores are more than 50nm. The coordination polymer material with a multistage pore passage structure is large in specific surface, the large-size organic ligand does not need to be synthesized, and the coordination polymer material with larger porous sizes can be obtained without the template agent and the pore assisting agent, so that the invention is simple in preparation method, and low in cost.

The invention relates to a benzothiazole derivatives metal coordination polymer based on a bridged bis-salicylaldehyde structure, characterized by having the following structure which is shown in the specification, wherein linker is CH2 or C(CH3)2, R is H+, halogen base, phenyl or biphenyl, and M is Zn2+, Be2+ or Ca2+. The benzothiazole derivatives metal coordination polymer has favorable thermal stability, good fluorescent emission performance and simple preparation method. The coordination polymer of the type can be applied to the organic electroluminescent material aspect.

The invention relates to liquid chelated calcium as well as a preparation method and use thereof and belongs to the chemical fertilizer filed in agricultural science and farming techniques. The invention provides the liquid chelated calcium and the preparation method thereof. Active ingredients of the liquid chelated calcium disclosed by the invention are prepared by chelating 45-70 parts by weight of calcium nitrate and 10-25 parts by weight of polyhydroxy compounds in water, wherein the polyhydroxy compounds are ethylene glycol, glycerol, mannitol, xylitol, sorbitol or glucose. The liquid chelated calcium disclosed by the invention is high in calcium content which is greater than 120 g / L, safe and non-toxic, free from harmful effect on crops, can be mixed with other pesticides, weakly-acidic and neutral fertilizers for use, good in water solubility for being conveniently mixed with water for using and metering, good in stability, and can be stored by resisting a low temperature; besides, the liquid chelated calcium is produced by adopting a chelating process, so that crops can be absorbed better and quicker.

The invention relates to Group 1 metal / silica gel compositions comprising silica gel and an alkali metal or an alkali metal alloy. The compositions of the inventions are described as Stage 0, I, II, and III materials. These materials differ in their preparation and chemical reactivity. Each successive stage may be prepared directly using the methods described below or from an earlier stage material. Stage 0 materials may, for example, be prepared using liquid alloys of Na and K which are rapidly absorbed by silica gel (porous SiO2) under isothermal conditions, preferably at or just above room temperature, to form loose black powders that retain much of the reducing ability of the parent metals. When the low melting Group 1 metals are absorbed into the silica gel, a mild exothermic reaction produces Stage I material, loose black powders that are indefinitely stable in dry air. Subsequent heating to 400° C. produces Stage II materials, which are also loose black powders. Further heating above 400° C. forms Stage III material with release of some Group 1 metal. It is believed that Stage I, II and III materials represent reductions of the silica gel after absorption of the Group 1 metal. Preferred Group 1 metal / silica gel compositions of the invention are those containing sodium, potassium, or sodium-potassium alloys with sodium and sodium-potassium alloys being most preferred. Each stage of the Group 1 metal / silica gel composition of the invention may be used as a reducing agent reacting with a number of reducible organic materials in the same manner known for alkali metals and their alloys.

An olefin metathesis catalyst and method for producing same is provided.

A process for producing an aromatic compound which can effectively decrease the contents of halogen elements in the aromatic compound and an aromatic compound which is produced in accordance with the process and useful as the material for obtaining an organic electroluminescence device having a long life are provided. The process for producing an aromatic compound comprises bringing an aromatic compound which is produced via an intermediate compound having halogen elements and has contents of halogen elements of 10 to 1,000 ppm by mass into reaction with a dehalogenating agent to decrease the contents of halogen elements to 10 ppm by mass or smaller, and an aromatic compound which is produced in accordance with the process.

Cyclopentadienyl and Indenyl barium / strontium metal precursors and Lewis base adducts thereof are described. Such precursors have utility for forming Ba- and / or Sr-containing films on substrates, in the manufacture of microelectronic devices or structures.

A process for stereoselective synthesis of compounds of Formula X wherein: R1 is an aryl or heteroaryl group, each optionally independently substituted with one to three substituent groups, wherein each substituent group of R1 is independently C1-C5 alkyl, C2-C5 alkenyl, C2-C5 alkynyl, C3-C8 cycloalkyl, heterocyclyl, aryl, heteroaryl, C1-C5 alkoxy, C2-C5 alkenyloxy, C2-C5 alkynyloxy, aryloxy, C1-C5 alkanoyloxy, C1-C5 alkanoyl, aroyl, trifluoromethyl, trifluoromethoxy, or C1-C5 alkylthio, wherein each substituent group of R1 is optionally independently substituted with one to three substituent groups selected from methyl, methoxy, fluoro, chloro, hydroxy, oxo, cyano, or amino; and R2 and R3 are each independently hydrogen or C1-C5 alkyl, or R2 and R3 together with the carbon atom they are commonly attached to form a C3-C8 spiro cycloalkyl ring.

A process for preparing a functionalized polymerization initiator, the process comprising combining a functionalized styryl compound and an organolithium compound.

This invention relates to a one pot method for large scale production of an organometallic compound comprising (i) reacting a hydrocarbon or heteroatom-containing material with a base material in the presence of a solvent and under reaction conditions sufficient to produce a first reaction mixture comprising a hydrocarbon or heteroatom-containing compound, (ii) adding a metal source compound to said first reaction mixture, (iii) reacting said hydrocarbon or heteroatom-containing compound with said metal source compound under reaction conditions sufficient to produce a second reaction mixture comprising said organometallic compound, and (iv) separating said organometallic compound from said second reaction mixture.

A process for stereoselective synthesis of compounds of Formula Xwherein:R1 is an aryl or heteroaryl group, each optionally independently substituted with one to three substituent groups,wherein each substituent group of R1 is independently C1-C5 alkyl, C2-C5 alkenyl, C2-C5 alkynyl, C3-C8 cycloalkyl, heterocyclyl, aryl, heteroaryl, C1-C5 alkoxy, C2-C5 alkenyloxy, C2-C5 alkynyloxy, aryloxy, C1-C5 alkanoyloxy, C1-C5 alkanoyl, aroyl, trifluoromethyl, trifluoromethoxy, or C1-C5 alkylthio,wherein each substituent group of R1 is optionally independently substituted with one to three substituent groups selected from methyl, methoxy, fluoro, chloro, hydroxy, oxo, cyano, or amino; andR2 and R3 are each independently hydrogen or C1-C5 alkyl, or R2 and R3 together with the carbon atom they are commonly attached to form a C3-C8 spiro cycloalkyl ring.

The invention discloses zinc, magnesium and calcium complexes of monophenol ligands with similar salan-structures as well as a preparation method thereof and the application in lactone ring-opening polymerization. The preparation method comprises the steps as follows: the similar salan-monophenol ligands react with zinc, magnesium and calcium metallo-organic compounds, and then target products are collected from reaction coarse products. The zinc, magnesium and calcium complexes comprise asymmetrical multidentate amino monophenol oxygroup ligands with the similar salan-structures, are effective lactone ring-opening polymerization catalysts, and can be used for ring-opening polymerization of lactide, caprolactone and the like. The multidentate monophenol oxygroup zinc, magnesium and calcium complexes have the very obvious advantages as follows: raw materials are easy to get, the synthetic route is simple, separation and purification are easy, and the performance is stable relatively; meanwhile, high catalytic activity is achieved; in addition, polylactone that is obtained through catalysis has higher molecular weight, and the requirements of industrial sectors can be satisfied. The structure of the zinc, magnesium and calcium complexes has the following general formula.

The present invention provides a raw material for forming a strontium-containing thin film of a cyclopentadienyl-based strontium compound, which is in the liquid state at room temperature to 50° C., can be purified by distillation, present as a monomer, has high vapor pressure, and suitable for mass production, and a process for preparing the same. Sr[C5(CH3)4(C3H7)]2 is prepared by reacting Na[C5(CH3)4(C3H7)]2 or K[C5(CH3)4(C3H7)]2 with SrI2 in THF to produce a THF adduct of Sr[C5(CH3)4(C3H7)]2; evaporating THF and extracting the residue with toluene to give a toluene solution; evaporating toluene and drying the residue under reduced pressure; and heating to 100 to 160° C. in vacuo to dissociate and remove THF and distilling.

The present invention relates to powder compositions of a complex between an acid and a metal and to the method for preparing same.

The present invention is directed to a reagent for use in the preparation of organomagnesium compounds as well as to a method of preparing such organomagnesium compounds. The present invention furthermore provides a method of preparing functionalized or unfunctionalized organic compounds as well as the use of the reagents of the present invention in the preparation of organometallic compounds and their reaction with electrophiles. Finally, the present invention is directed to the use of lithium salts—LiY in the preparation of organometallic compounds and their reactions with electrophiles and to an organometallic compound which is obtainable by the disclosed method.

A process for preparing a functionalized polymerization initiator, the process comprising combining a functionalized styryl compound and an organolithium compound.

An alkannin derivative as immuno-suppressive agent and its metallic complex compound with a chemical constitution formulas III and IV disclosed in the specification, wherein in formula III, R is C1-6 saturated, unsaturated and aromatic acyl, in formula IV, R is hydrogen, C1-6 saturated, unsaturated and aromatic acyl, M is metallic Cu, Ca, Zn. The present invention realizes immunological suppression effect, thus can be used for treating diseases relating to human body autoimmune including chronic infectious arthritis, scleredema, lupus erythematosus, HIV infection and malignant tumor.

The invention provides a metallic alkoxy complex of which the molecular formula is disclosed as Formula (I). The invention also provides a catalyst composition which comprises the metallic alkoxy complex and a hydroxy compound, wherein the mol ratio of the metallic alkoxy complex to the hydroxy compound is 1:(0.1-1000). The preparation method of the poly-epsilon-caprolactone or poly-actide comprises the following steps: reacting an epsilon-caprolactone monomer or lactide monomer under the action of the metallic alkoxy complex or the catalyst composition to obtain poly-epsilon-caprolactone or poly-actide. The metallic alkoxy complex and the catalyst composition thereof can efficiently catalyze the synthesis of the poly-epsilon-caprolactone or poly-actide. The molecular weight of the poly-caprolactone or poly-actide can be controlled by the mol ratio of the metallic alkoxy complex to the hydroxy compound, and can be adjusted within the range of 1-600 thousand, and the molecular weight distribution ranges from 1.03 to 1.50.

A process for the preparation of the calcium complex of 10-(2, 3-Dihydroxy-1-(hydroxymethyl)propyl)-1,4,7,10-tetraazacyclodecane-4,7-triacetic acid, also known as Calcobutrol, starting from the pure gadolinium complex (Gadobutrol) is disclosed. Also disclosed is Calcobutrol with a hitherto unknown level of purity.

[PROBLEMS] To provide a metal complex compound capable of being suitably used for manufacturing a metal-containing thin film by the CVD method and a method for preparing a metal-containing thin film.[MEANS FOR SOLVING PROBLEMS] A metal complex compound comprising a β-diketonato ligand having an alkoxyalkyl-methyl group, and a method for preparing a metal-containing thin film using the metal complex compound by the CVD method.

The present invention provides a raw material for forming a strontium-containing thin film of a cyclopentadienyl-based strontium compound, which is in the liquid state at room temperature to 50° C., can be purified by distillation, present as a monomer, has high vapor pressure, and suitable for mass production, and a process for preparing the same. Sr[C5(CH3)4(C3H7)]2 is prepared by reacting Na[C5(CH3)4(C3H7)]2 or K[C5(CH3)4(C3H7)]2 with SrI2 in THF to produce a THF adduct of Sr[C5(CH3)4(C3H7)]2; evaporating THF and extracting the residue with toluene to give a toluene solution; evaporating toluene and drying the residue under reduced pressure; and heating to 100 to 160° C. in vacuo to dissociate and remove THF and distilling.

An alkaline earth metal salt of beta-diketo compound is produced using 1 mol of a powdery alkaline earth metal compound and 2.04 mol or more of an aliphatic beta-diketo compound. The reaction may be carried out while supplying both components to a reactor continuously or intermittently, or may be carried out by adding one component to the other continuously or intermittently. The highest temperature during the reaction may be at 50° C. or higher. The reaction mixture may be aged, and then dried at a temperature of at 100 to 180° C. in an atmosphere of an inert gas. The alkaline earth metal compound may be calcium hydroxide, magnesium hydroxide, or barium hydroxide. The aliphatic beta-diketo compound may be represented by the following formula, particularly an acetoacetic acid ester or acetylacetone.According to the production method as mentioned above, highly stable alkaline earth metal salts of beta-diketo compounds of high quality can be produced.

The invention relates to a method for preparing a compound comprising at least one β-hydroxy-urethane unit and / or at least one γ-hydroxy-urethane unit, consisting in reacting a compound (A) comprising at least one cyclocarbonate reactive unit with a compound (B) comprising at least one amino reactive unit (—NH2) in the presence of a catalyst. The invention also relates to the use of a catalyst comprising at least one organometallic complex and a co-catalyst chosen from the group of Lewis bases and / or tetra-alkyl ammonium salts, in order to catalyse the method of the invention. The invention relates to the technical field of preparing urethane derivatives.

The claimed invention meets these and other objects by providing a method of preparing a metal salt of a dialkyl ester of 5-sulfoisophthalic acid. Broadly speaking, the method provides for the contacting of a dialkyl ester of 5-sulfoisophthalic acid with a metal cation in a buffered reaction mixture to form the metal salt of the dialkyl ester. The reaction mixture is buffered, at least in part, by the acetate of the metal cation. The method according to invention also encompasses various methods of preparing the dialkyl ester of 5-sulfoisophthalic acid.

Barium, strontium, tantalum and lanthanum precursor compositions useful for atomic layer deposition (ALD) and chemical vapor deposition (CVD) of titanate thin films. The precursors have the formula M(Cp)2, wherein M is strontium, barium, tantalum or lanthanum, and Cp is cyclopentadienyl, of the formula (I), wherein each of R1-R5 is the same as or different from one another, with each being independently selected from among hydrogen, C1-C12 alkyl, C1-C12 amino, C6-C10 aryl, C1-C12 alkoxy, C3-C6 alkylsilyl, C2-C12 alkenyl, R1R2R3NNR3, wherein R1, R2 and R3 may be the same as or different from one another and each is independently selected from hydrogen and C1-C6 alkyl, and pendant ligands including functional group(s) providing further coordination to the metal center M. The precursors of the above formula are useful to achieve uniform coating of high dielectric constant materials in the manufacture of flash memory and other microelectronic devices.

A method of manufacturing an amorphous form of the hemi-calcium salt of (3R, 5R) 7-[3-phenyl-4-phenylcarbamoyl-2-(4-fluorophenyl)-5-isopropyl-pyrrol-1-yl]-3,5-dihydroxyheptanoic acid of formula (I), in which (3R, 5R) 7-[3-phenyl-4-phenylcarbamoyl-2-(4-fluorophenyl)-5-isopropyl-pyrrol-1-yl]-3,5-dihydroxyheptanoic acid or its salt with a cation M+ wherein M30 is either a cation of an alkali metal or an ammonium cation of formula RnN(+)H(4−n) wherein R is lower C1-C5 alkyl, n may reach values ranging between 0 and 3, is, without isolating the intermediate in the form of the hemi-calcium salt or of another salt, acid or lactone, converted, in a solution, by the treatment with the calcium salt or calcium hydroxide, or a calcium C1-C5 alcoholate, to the hemi-calcium salt, and the latter is precipitated with a C1-C5hydrocarbon or dialkylether of formula R1OR2, wherein each of R1 and R2 is a C1-C5 alkyl group. The starting acid or its salt is prepared starting from (3R, 5R) tert-butyl (6-{2-[3-phenyl-4-phenylcarbamoyl-2-(4-fluorophenyl)-5-isopropyl-pyrrol-1-yl]-ethyl}-2,2-dimethyl-[1,3]dioxane-4-yl)acetate of formula II.

The invention provides four types of metal complexes. The four types of metal complexes have structures shown as a formula (I), a formula (II), a formula (III) or a formula (IV) described in the specification respectively, and have high independent catalytic activity on the polymerization of epsilon-caprolactone or a lactide monomer. The molecular weight distribution of a polymerization product is narrower. The invention further provides a catalyst composition, which consists of the metal complex with a structure shown as the formula (I), formula (II), formula (III) or formula (IV) and alcohol. The catalyst composition can be used for efficiently catalyzing polymerization of epsilon-caprolactone or the lactide monomer, and the molar ratio of the alcohol to the complex can be changed in a large range such as (0.1-100):1. The molecular weight of a polymer can be controlled by means of the molar ratio of the alcohol to the complex and is adjustable in the range 2,000-600,000, and the molecular weight distribution is 1.01-1.66.

The invention provides an acetylacetone metal component, a precreation method for the acetylacetone metal component, a plastic and the application of heat stabilizer. The acetylacetone metal component has the following general formula: (OH)x.A<n+>y.Bz, wherein A expresses a metal ion, n expresses the valence of the metal ion, B expresses an acetylacetone anion, and a relationship among n, x, y and z is n*y=x+z. Metal hydroxide or metallic oxide reacts with salt of acetylacetonate to obtain the acetylacetone metal component. By use of the acetylacetone metal component disclosed by the invention, cost is lowered, and characteristic odors are reduced. The acetylacetone metal component is used for the plastic (especially polyvinyl chloride) as the heat stabilizer, and the heat stabilization effect of the acetylacetone metal component is equivalent to the heat stabilization effect of traditional calcium acetylacetonate.