The invention discloses waterproof leather prepared via
polymerization deposition of low-temperature plasmas and a preparation method of the waterproof leather. The method comprises the following steps: vaporizing
siloxane monomers or crylic acid monomers or
acrylate monomers or fluorinated
acrylate monomers or fluorosilane monomers under the vacuum degree of 25Pa to 45Pa at the temperature of 25 DEG C to 50 DEG C; then adding the vaporized monomers into
plasma reaction equipment according to a certain flow and reacting for 1 to 25 minutes under the
discharge power within 0.15W / cm<2> to 1.5W / cm<2>; and depositing the monomers on the leather in the
plasma reaction equipment, wherein the thickness of a waterproof membrane deposited on the surface of the leather in a
polymerization manner is in a micron level or below the micron level, the static
contact angle of the waterproof membrane is within 136 DEG to 155 DEG and the
rolling angle of the waterproof membrane is within 7 DEG to 22 DEG, and stagger collagen fibers can be seen clearly by observing through a
scanning electron microscope. The method is simple in treatment process, short in time, high in efficiency and low in
energy consumption. The obtained waterproof membrane is thin, and not only can maintain the real leather feeling of the surfaces of stone washed leathers, suede leathers, double-purpose leathers and the like but also can maintain the
sanitation performance of nature leathers.