The application provides a treatment method of epitaxial high-concentration
arsenic-containing
wastewater, comprising the following steps: adding
calcium hypochlorite into the epitaxial high-concentration
arsenic-containing
wastewater, and stirring and aerating; then adding
ferric chloride, and stirring and aerating; then using
lime milk solution to adjust the pH of the
system to 6.5-7, and continuing to stir and aerate; performing pressure
filtration to obtain primary
arsenic-containing
wastewater; adding
calcium chloride solution and
ferric chloride solution into the primary arsenic-containing wastewater obtained by pressure
filtration, using
lime milk solution to adjust the pH of the
system to 6.5-7, and then standing, taking supernatant to test, discharging the supernatant after reaching the standard; if the supernatant does not reach the standard, continuously adding
calcium chloride solution and
ferric chloride solution for cyclic treatment until the supernatant reaches the standard and is discharged. The method has the advantages of small
reagent dosage, low cost, high arsenic removal rate, high stability of arsenic-containing
hazardous waste and the like, and after being treated by the method, the arsenic content is lower than 0.3 mg / L, which meets the national
discharge standard.