The invention relates to the technical field of wireless charging of an electric vehicle, and particularly relates to an optical storage-type electric vehicle wireless power supply system laid in a highway and an open environment, which comprises the highway or a ground in the open environment, the electric vehicle, at least one charging system transmitting unit and an electric vehicle device receiving unit, wherein the charging system transmitting unit comprises a power supply module, a high-frequency inversion module, a pressure sensing device, an RFID reader, a power control circuit, a power oscillation module and an electromagnetic transmission coil connected in sequence; the electric vehicle device receiving unit comprises an electromagnetic receiving coil, an RFID electronic label, a rectifier module, a voltage-stabilizing step-down module and a vehicle-mounted battery connected in sequence; the high-frequency inversion module converts low-voltage DC to high-frequency AC; the at least one charging system transmitting unit is laid in the highway of the ground in the open environment to form a charging area; and the electric vehicle device receiving unit is arranged in the electric vehicle. The power supply system has a high energy utilization rate, and 24-hour uninterrupted power supply can be realized.