The invention relates to a special sampling
bottle for collecting a
water sample containing a
volatile substance and an
oxygen-sensitive substance. The special sampling
bottle structurally comprises a
bottle body for accommodating the
water sample, a bottle cover covering the upper opening of the bottle body, and a
plunger mechanism plugging the top opening in the center of the bottle cover, wherein the
plunger mechanism comprises a fixed
pipe, a T-shaped padding plug and a protection cap. Due to a special bottle body structure and a special bottle cover structure, the bottle cover and the bottle body can synchronously
discharge a certain amount of water in the
bottleneck in a buckling process, so that the sampling bottle is not required to be vertical absolutely no matter whether the site is flat or not; after the sampling bottle is full of the
water sample, even if certain water-sample-free redundant spaces are retained in the
bottleneck, all the redundant spaces other than the water sample in the
bottleneck can be discharged during filling type buckling of an inner sealing cover as long as the volumes of the retained spaces are smaller than the extruded volume of the inner sealing cover on the bottle cover; therefore the sampling bottle can be full of the water sample, no redundant space is retained, and sampling can be succeeded at one step.