The invention relates to natural traditional Chinese medicine mask powder as well as a preparation method and a mask thereof. The natural traditional Chinese medicine mask powder is prepared from the following raw materials in parts by weight: 7-23 parts of angelica sinensis, 3-14 parts of radix angelicae, 3-13 parts of radix paeoniae alba, 17-33 parts of bighead atractylodes rhizome, 3-20 parts of common bletilla tuber, and 3-15 parts of white poria. The raw materials also can be further added as follows: 12-28 parts of tribulus terrestris, 1-8 parts of liquorice and 1-8 parts of pearl powder. By cleaning and baking the specific parts of angelica sinensis, radix angelicae, radix paeoniae alba, bighead atractylodes rhizome, common bletilla tuber and white poria, and further added tribulus terrestris, liquorice and pearl powder and grinding into powder, so that a natural traditional Chinese medicine mask is obtained. The natural traditional Chinese medicine mask powder can be further mixed with water or egg white so as to be blended into a paste mask for a user to use. The components are in synergistic interaction, the natural traditional Chinese medicine mask powder is applicable to all types of skin, and is used for improving various skin problems such as acnes, chromatosis and wrinkles, and the product is free of other added ingredients.