The invention discloses a quick crosslinked ethylene-vinyl acetate copolymer (EVA) adhesive film for a double-glazed module, and a preparation method of the EVA adhesive film. The EVA adhesive film is prepared by mixing an EVA, a compatibilizer, a photoinitiator, a crosslinking agent, a defoaming agent and an antioxidant. The preparation method comprises the following steps: A. evenly mixing the EVA with the photoinitiator, the crosslinking agent, the compatibilizer, the defoaming agent and the antioxidant; B. evenly mixing the raw materials in a high mixing machine, and putting the mixture into an extruder for mixing, wherein the temperature of the extruder is controller to be within a range of 80-120 DEG C; C. carrying out tape casting, embossing, cooling, ultraviolet (UV)-curing and prepolymerization to form a film; carrying traction cutting, and finally winding to obtain the EVA adhesive film; D. packaging photovoltaic coated glass, a battery piece or the double-glazed module by means of the quick crosslinked EVA adhesive film for the double-glazed module. The method provided by the invention is easy to implement, simple and convenient to operate and lower in cost, reduces the processing time of the double-glazed module, and does not generate a merged piece; the defoaming agent is adopted as the raw material, so that the module is improved to be free from bubbles, and the yield of double-glazed modules is increased to be more than 99%; the preparation method is suitable for large-scale production.