The invention discloses a method for preparing a superconductive nanometer device by a negative 
electron beam 
resist exposure process. The method mainly comprises the following steps of: 
spinning a 
hydrogen silsesquioxane (HSQ) 
resist on a superconductive thin film; pre-
drying; designing an 
exposure graph; exposing by two steps; developing; fixing; and 
etching. By using the method, the superconductive nanometer device which is stable in performance and uniform in 
line width and has the minimum 
line width of 15 nm can be prepared. Residues do not exist in an 
electrode region after the 
etching step is performed by setting an 
exposure amount in different regions and changing the thickness of an exposure product in the corresponding region, so that electrical measurement is facilitated. HSQ has high anti-
etching performance and is suitable to serve as an etching 
mask of a hard superconductive 
metal material, so that the etching selection ratio can be increased. An 
electrode and the device are obtained through one-time etching; no contact 
potential difference exists between the 
electrode and the device; and the success rate of the device is high. Furthermore, a plurality of independent micro electric bridges are exposed on the same thin film, so that the efficiency of integrating and measuring the electric bridges can be improved, and the material 
utilization rate is increased; and the superconductive nanometer device has great significance for research on nanometer structures made of rare materials.