The invention provides an electroforming solution for a gold cyanide-free electroforming process and an electroforming process. 1 liter of the electroforming solution comprises 25-30 g of gold chloride gold salt, 60-80 g of anhydrous sodium sulfite, 50-70 g of sodium chloride, a hardening agent, anhydrous saccharin sodium salt, tellurium dioxide, ammonia water and phosphoric acid, wherein a mass ratio of an addition amount of the hardening agent to an addition amount of gold trichloride gold salt is 1: 1, and a mass ratio of an addition amount of the anhydrous saccharin sodium salt to an addition amount of the gold chloride gold salt is 1: (45-55). The process comprises the following steps of taking a wax mold as an electroforming model, and conducting copper plating after silver oil soaking, so as to plate the wax mold with a bright copper coating; conducting electrolytic degreasing, acid pickling activation and water washing deacidification; and conducting gold electroforming through the electroforming solution, and removing a mold core of the electroforming model after electroforming, so as to obtain a gold product. According to the electroforming solution and the electroforming process, an electroforming liquid system is stable, the service life is long, and the high-frequency problems of brittle fracture, soft surface collapse, interlayer peeling, hard spots and roughing, pores and needle holes and the like of products cast by an existing similar sulfite casting liquid system are solved.