The invention discloses an environment-friendly boiler waste heat recovery device for heat recovery based on heat layering, and belongs to the technical field of heat recovery. The environment-friendly boiler waste heat recovery device for heat recovery based on heat layering comprises a base, wherein the top of the base is connected with a slag chamber, the top of the slag chamber is connected with a combustion chamber, a fuel port is formed in the outer wall of the combustion chamber, a chamber door is arranged on the outer wall of the fuel port, ventilation holes which are uniformly distributed are formed in the outer wall of the chamber door, a material turning mechanism is arranged in the combustion chamber, the end, far away from the slag chamber, of the combustion chamber is connected with a heating water tank, a shell sleeves the outer wall of the heating water tank, a first support is connected between the shell and the base, and a smoke outlet used for discharging smoke is formed in the outer wall of the top of the combustion chamber. According to the environment-friendly boiler waste heat recovery device, fuel can be completely combusted, so that harmful gas in the smoke generated after combustion is reduced, and environmental protection is facilitated; and meanwhile, the heat energy of the smoke after combustion is utilized, preheating is carried out before water body heating, so that the fuel consumption is reduced, the water boiling time is shortened, and the resource utilization rate is improved.