The apparatus for determining the dew-point and/or the content of vapor in the air, particularly for the use in radio sondes, comprises a dew-point mirror assembly, including a source of light, a reflector, a cooling element thermally coupled to the reflector, a temperature sensor for measuring the temperature of the reflector, and a detecting sensor for receiving the light emitted by the light source and reflected by the reflector. The detecting sensor is located in a temperature stabilized region of the apparatus and optically coupled to the reflector by means of a light wave conductor. The light source is an incandescent lamp. A sensor head is provided that receives the reflector, the cooling element, the light source, and the input end of the light wave conductor. The sensor head is heated by means of an active heating element. For exactly determining the temperature of the reflector, a combination thermo element/reflector is proposed, whereby the thermo element is constituted by two sheet metal plate members soldered to each other face to face. The surface of one of the sheet metal plate members is highly reflective and constitutes the reflector. With the help of such an apparatus, the dew-point and/or the content of vapor in the air can be determined very accurately.