The application relates to the technical field of SCGD-OES online detection, and specifically provides a multi-element online quantitative method,
system, equipment and medium of a high-salt
matrix solution, which comprises the following steps: synchronously collecting multi-
modal data; constructing a
state vector according to the multi-
modal data; calculating a
stability index through
robust principal component analysis and
Mahalanobis distance; combining with working condition parameters to distinguish the working condition and the stability state; and adaptively selecting a quantitative analysis mode; under the working condition constraint, inputting
spectral line characteristics into a segmented weighted least square regression model which is fused with monotonicity constraint, multi-
spectral line consistency and self-absorption /
quenching penalty term, compensating for the matrix effect and calculating the concentration; and finally, fusing the
stability index,
spectral line consistency deviation and model residual error to calculate the comprehensive confidence, and outputting the concentration and the confidence. The application improves the accuracy, robustness and result reliability of multi-element
online analysis under high-salt, dynamic and nonlinear complex working conditions.