The invention discloses an intelligent fire-fighting water monitor fire extinguishing system and a fire extinguishing agent thereof. The intelligent fire-fighting water monitor fire extinguishing system comprises a central controller, a video identifying system and a fire-fighting water monitor device. The central controller consists of a host and a monitor display screen. The video identifying system consists of an intelligent detector, a signal processor and a data transmission device. The fire-fighting water monitor device consists of a bracket and a water monitor. The fire extinguishing agent is obtained through the steps that water and polyacrylamide are mixed, heating is conducted, sodium bicarbonate is added, mixing is conducted to dissolving, gelatin, nano-zinc oxide, nano-magnesium hydroxide, ammonium magnesium phosphate, polyethylene glycol, carbonic esters with aromatic groups and protein phenol ethyoxyl polymer are mixed under high-speed stirring, octadecyl benzene sulfonicacid sodium salt is added, a reaction is conducted, and the fire extinguishing agent is obtained. According to the intelligent fire-fighting water monitor fire extinguishing system, fire extinguishing can be achieved in a large space, the structure is simple, graded fire extinguishing of the fire extinguishing agent and water is adopted, the fire extinguishing efficiency is high, the extinguishing agent technology of the intelligent fire-fighting water monitor fire extinguishing system is simple, and the extinguishing agent can cover the surface of burning debris to isolate air.