The invention discloses a large-deviation-rectifying-force pile holding machine and an operation process thereof. The machine comprises a ship deck, double H-shaped steel rails, an upper platform, round stand columns, a stand column assembly, a pull cable, left pile claw arms, right pile claw arms, a pile claw tail oil cylinder, middle contacts, a stand column stretching-out box body, a locking device, end contacts, end plug pin mechanisms and tail positioning contacts. The double H-shaped steel rails are fixedly mounted on the upper surface of the ship deck; the upper platform is fixedly mounted at the top ends of the double-H-shaped steel rails; two round stand columns and the stand column assembly are fixedly installed on the upper surface of the upper platform; the number of the left pile claw arms and the number of the right pile claw arms are both two; the middle contacts, the end contacts and the tail positioning contacts are mounted on the inner sides of the left pile claw armsand the right pile claw arms; and one end, away from the connecting round stand column, of the stand column stretching-out box body is flexibly connected with a locking device, and one end, away fromthe connected round stand column, of each left pile claw arm is equipped with the end plug pin mechanism. According to the invention, the structure and the operation process are reasonable, deviationrectification can be conducted in time, the working efficiency is greatly improved, the applicability is high, and the overall service life is greatly prolonged.